A permanent mesoporous organic cage with an exceptionally high surface area

Recently, porous organic cage crystals have become a real alternative to extended framework materials with high specific surface areas in the desolvated state. Although major progress in this area has been made, the resulting porous compounds are restricted to the microporous regime, owing to the re...

Full description

Saved in:
Bibliographic Details
Main Authors: Zhang, Gang (Author) , Presly, Oliver (Author) , White, Fraser (Author) , Oppel, Iris M. (Author) , Mastalerz, Michael (Author)
Format: Article (Journal)
Language:English
Published: 08 January 2014
In: Angewandte Chemie. International edition
Year: 2014, Volume: 53, Issue: 6, Pages: 1516-1520
ISSN:1521-3773
DOI:10.1002/anie.201308924
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201308924
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201308924
Get full text
Author Notes:Gang Zhang, Oliver Presly, Fraser White, Iris M. Oppel, and Michael Mastalerz

MARC

LEADER 00000caa a2200000 c 4500
001 1734806400
003 DE-627
005 20230427033741.0
007 cr uuu---uuuuu
008 201006s2014 xx |||||o 00| ||eng c
024 7 |a 10.1002/anie.201308924  |2 doi 
035 |a (DE-627)1734806400 
035 |a (DE-599)KXP1734806400 
035 |a (OCoLC)1341368328 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Zhang, Gang  |e VerfasserIn  |0 (DE-588)1210714280  |0 (DE-627)169867774X  |4 aut 
245 1 2 |a A permanent mesoporous organic cage with an exceptionally high surface area  |c Gang Zhang, Oliver Presly, Fraser White, Iris M. Oppel, and Michael Mastalerz 
264 1 |c 08 January 2014 
300 |a 5 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Gesehen am 06.10.2020 
520 |a Recently, porous organic cage crystals have become a real alternative to extended framework materials with high specific surface areas in the desolvated state. Although major progress in this area has been made, the resulting porous compounds are restricted to the microporous regime, owing to the relatively small molecular sizes of the cages, or the collapse of larger structures upon desolvation. Herein, we present the synthesis of a shape-persistent cage compound by the reversible formation of 24 boronic ester units of 12 triptycene tetraol molecules and 8 triboronic acid molecules. The cage compound bears a cavity of a minimum inner diameter of 2.6 nm and a maximum inner diameter of 3.1 nm, as determined by single-crystal X-ray analysis. The porous molecular crystals could be activated for gas sorption by removing enclathrated solvent molecules, resulting in a mesoporous material with a very high specific surface area of 3758 m2 g−1 and a pore diameter of 2.3 nm, as measured by nitrogen gas sorption. 
650 4 |a boronic acids 
650 4 |a cage compounds 
650 4 |a dynamic covalent chemistry 
650 4 |a porosity 
650 4 |a triptycene 
700 1 |a Presly, Oliver  |e VerfasserIn  |4 aut 
700 1 |a White, Fraser  |e VerfasserIn  |4 aut 
700 1 |a Oppel, Iris M.  |d 1970-  |e VerfasserIn  |0 (DE-588)142964085  |0 (DE-627)704352834  |0 (DE-576)334334853  |4 aut 
700 1 |a Mastalerz, Michael  |d 1972-  |e VerfasserIn  |0 (DE-588)130559431  |0 (DE-627)503822701  |0 (DE-576)298267950  |4 aut 
773 0 8 |i Enthalten in  |t Angewandte Chemie. International edition  |d Weinheim : Wiley-VCH, 1998  |g 53(2014), 6, Seite 1516-1520  |h Online-Ressource  |w (DE-627)320497879  |w (DE-600)2011836-3  |w (DE-576)111552060  |x 1521-3773  |7 nnas  |a A permanent mesoporous organic cage with an exceptionally high surface area 
773 1 8 |g volume:53  |g year:2014  |g number:6  |g pages:1516-1520  |g extent:5  |a A permanent mesoporous organic cage with an exceptionally high surface area 
856 4 0 |u https://doi.org/10.1002/anie.201308924  |x Verlag  |x Resolving-System  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201308924  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20201006 
993 |a Article 
994 |a 2014 
998 |g 130559431  |a Mastalerz, Michael  |m 130559431:Mastalerz, Michael  |d 120000  |d 120100  |e 120000PM130559431  |e 120100PM130559431  |k 0/120000/  |k 1/120000/120100/  |p 5  |y j 
998 |g 1210714280  |a Zhang, Gang  |m 1210714280:Zhang, Gang  |p 1  |x j 
999 |a KXP-PPN1734806400  |e 3768832058 
BIB |a Y 
SER |a journal 
JSO |a {"language":["eng"],"title":[{"title_sort":"permanent mesoporous organic cage with an exceptionally high surface area","title":"A permanent mesoporous organic cage with an exceptionally high surface area"}],"recId":"1734806400","origin":[{"dateIssuedKey":"2014","dateIssuedDisp":"08 January 2014"}],"name":{"displayForm":["Gang Zhang, Oliver Presly, Fraser White, Iris M. Oppel, and Michael Mastalerz"]},"person":[{"role":"aut","display":"Zhang, Gang","given":"Gang","family":"Zhang"},{"family":"Presly","display":"Presly, Oliver","given":"Oliver","role":"aut"},{"given":"Fraser","display":"White, Fraser","family":"White","role":"aut"},{"family":"Oppel","given":"Iris M.","display":"Oppel, Iris M.","role":"aut"},{"role":"aut","family":"Mastalerz","display":"Mastalerz, Michael","given":"Michael"}],"relHost":[{"note":["Gesehen am 20.12.2022","Fortsetzung der Druck-Ausgabe"],"part":{"volume":"53","text":"53(2014), 6, Seite 1516-1520","pages":"1516-1520","year":"2014","issue":"6","extent":"5"},"id":{"zdb":["2011836-3"],"issn":["1521-3773"],"doi":["10.1002/(ISSN)1521-3773"],"eki":["320497879"]},"physDesc":[{"extent":"Online-Ressource"}],"title":[{"title":"Angewandte Chemie","subtitle":"a journal of the Gesellschaft Deutscher Chemiker","title_sort":"Angewandte Chemie","partname":"International edition"}],"corporate":[{"role":"isb","display":"Gesellschaft Deutscher Chemiker"}],"origin":[{"publisherPlace":"Weinheim","dateIssuedKey":"1998","dateIssuedDisp":"1998-","publisher":"Wiley-VCH"}],"type":{"bibl":"periodical","media":"Online-Ressource"},"pubHistory":["37.1998 -"],"titleAlt":[{"title":"Angewandte Chemie / International edition"}],"language":["eng"],"disp":"A permanent mesoporous organic cage with an exceptionally high surface areaAngewandte Chemie. International edition","recId":"320497879"}],"note":["Gesehen am 06.10.2020"],"type":{"media":"Online-Ressource","bibl":"article-journal"},"id":{"doi":["10.1002/anie.201308924"],"eki":["1734806400"]},"physDesc":[{"extent":"5 S."}]} 
SRT |a ZHANGGANGPPERMANENTM0820