Catalytic oxidation of alkanes by iron bispidine complexes and dioxygen: oxygen activation versus autoxidation
Organic substrates (specifically cis-1,2-dimethylcyclohexane, DMCH) are oxidized by O2 in the presence of iron(II)-bispidine complexes. It is shown that this oxidation reaction is not based on O2 activation by the nonheme iron catalysts as in Nature but due to a radical-based initiation, followed by...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2014
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| In: |
Chemical communications
Year: 2013, Jahrgang: 50, Heft: 4, Pages: 412-414 |
| ISSN: | 1364-548X |
| DOI: | 10.1039/C3CC47013J |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1039/C3CC47013J Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2014/cc/c3cc47013j 
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| Verfasserangaben: | Peter Comba, Yong-Min Lee, Wonwoo Nam and Arkadius Waleska |
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| 520 | |a Organic substrates (specifically cis-1,2-dimethylcyclohexane, DMCH) are oxidized by O2 in the presence of iron(II)-bispidine complexes. It is shown that this oxidation reaction is not based on O2 activation by the nonheme iron catalysts as in Nature but due to a radical-based initiation, followed by a radical- and ferryl-based catalytic reaction. | ||
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