Mechanistic insights into the gold chemistry of allenes
Although most mechanistic studies on gold-catalysed reactions focused on alkynes as substrates, some knowledge about gold-catalysed conversions of allenic substrates has been obtained. This contribution summarises these insights into the reaction mechanisms of gold-catalysed transformations of allen...
Gespeichert in:
| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
27 March 2014
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| In: |
Chemical Society reviews
Year: 2014, Jahrgang: 43, Heft: 9, Pages: 2941-2955 |
| ISSN: | 1460-4744 |
| DOI: | 10.1039/C3CS60441A |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C3CS60441A Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2014/cs/c3cs60441a 
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| Verfasserangaben: | Weibo Yang and A. Stephen K. Hashmi |
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| 520 | |a Although most mechanistic studies on gold-catalysed reactions focused on alkynes as substrates, some knowledge about gold-catalysed conversions of allenic substrates has been obtained. This contribution summarises these insights into the reaction mechanisms of gold-catalysed transformations of allenes which are based on computational studies, labelling studies, the detection of intermediates, chirality transfer and diastereoselective product formation. | ||
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