Enantio- and regioselective iridium-catalyzed allylic esterification
A highly enantioselective and regioselective Ir-catalyzed allylic esterification is described, in which branched allylic esters are synthesized directly. Carboxylates were used as nucleophiles and linear allylic phosphates as electrophiles. In some cases the allylic substitution reaction was found t...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article (Journal) |
| Language: | English |
| Published: |
January 14, 2014
|
| In: |
Journal of the American Chemical Society
Year: 2014, Volume: 136, Issue: 4, Pages: 1272-1275 |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/ja411869r |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ja411869r Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/ja411869r 
|
| Author Notes: | Jianping Qu, Lydia Roßberg, and Günter Helmchen |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1735353604 | ||
| 003 | DE-627 | ||
| 005 | 20230427161416.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 201012s2014 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/ja411869r |2 doi | |
| 035 | |a (DE-627)1735353604 | ||
| 035 | |a (DE-599)KXP1735353604 | ||
| 035 | |a (OCoLC)1341370900 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Qu, Jianping |e VerfasserIn |0 (DE-588)1160111677 |0 (DE-627)1023269821 |0 (DE-576)505527898 |4 aut | |
| 245 | 1 | 0 | |a Enantio- and regioselective iridium-catalyzed allylic esterification |c Jianping Qu, Lydia Roßberg, and Günter Helmchen |
| 264 | 1 | |c January 14, 2014 | |
| 300 | |a 4 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 12.10.2020 | ||
| 520 | |a A highly enantioselective and regioselective Ir-catalyzed allylic esterification is described, in which branched allylic esters are synthesized directly. Carboxylates were used as nucleophiles and linear allylic phosphates as electrophiles. In some cases the allylic substitution reaction was found to be accompanied by a kinetic resolution process, which causes a change of the enantiomeric excess. | ||
| 700 | 1 | |a Roßberg, Lydia |e VerfasserIn |0 (DE-588)1079104291 |0 (DE-627)840209509 |0 (DE-576)452196957 |4 aut | |
| 700 | 1 | |a Helmchen, Günter |e VerfasserIn |0 (DE-588)115539689 |0 (DE-627)691390134 |0 (DE-576)289938902 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |a American Chemical Society |t Journal of the American Chemical Society |d Washington, DC : ACS Publications, 1879 |g 136(2014), 4, Seite 1272-1275 |w (DE-627)268132836 |w (DE-600)1472210-0 |w (DE-576)090854284 |x 1520-5126 |7 nnas |
| 773 | 1 | 8 | |g volume:136 |g year:2014 |g number:4 |g pages:1272-1275 |g extent:4 |a Enantio- and regioselective iridium-catalyzed allylic esterification |
| 856 | 4 | 0 | |u https://doi.org/10.1021/ja411869r |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://pubs.acs.org/doi/10.1021/ja411869r |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20201012 | ||
| 993 | |a Article | ||
| 994 | |a 2014 | ||
| 998 | |g 115539689 |a Helmchen, Günter |m 115539689:Helmchen, Günter |d 120000 |d 120100 |e 120000PH115539689 |e 120100PH115539689 |k 0/120000/ |k 1/120000/120100/ |p 3 |y j | ||
| 998 | |g 1079104291 |a Roßberg, Lydia |m 1079104291:Roßberg, Lydia |d 120000 |d 120100 |e 120000PR1079104291 |e 120100PR1079104291 |k 0/120000/ |k 1/120000/120100/ |p 2 | ||
| 998 | |g 1160111677 |a Qu, Jianping |m 1160111677:Qu, Jianping |d 120000 |d 120100 |e 120000PQ1160111677 |e 120100PQ1160111677 |k 0/120000/ |k 1/120000/120100/ |p 1 |x j | ||
| 999 | |a KXP-PPN1735353604 |e 3778827170 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"title":[{"title":"Enantio- and regioselective iridium-catalyzed allylic esterification","title_sort":"Enantio- and regioselective iridium-catalyzed allylic esterification"}],"person":[{"role":"aut","roleDisplay":"VerfasserIn","display":"Qu, Jianping","given":"Jianping","family":"Qu"},{"given":"Lydia","family":"Roßberg","role":"aut","display":"Roßberg, Lydia","roleDisplay":"VerfasserIn"},{"roleDisplay":"VerfasserIn","display":"Helmchen, Günter","role":"aut","family":"Helmchen","given":"Günter"}],"note":["Gesehen am 12.10.2020"],"type":{"bibl":"article-journal","media":"Online-Ressource"},"language":["eng"],"recId":"1735353604","origin":[{"dateIssuedKey":"2014","dateIssuedDisp":"January 14, 2014"}],"id":{"eki":["1735353604"],"doi":["10.1021/ja411869r"]},"name":{"displayForm":["Jianping Qu, Lydia Roßberg, and Günter Helmchen"]},"physDesc":[{"extent":"4 S."}],"relHost":[{"title":[{"subtitle":"JACS","title":"Journal of the American Chemical Society","title_sort":"Journal of the American Chemical Society"}],"titleAlt":[{"title":"JACS"},{"title":"web edition"}],"part":{"extent":"4","volume":"136","text":"136(2014), 4, Seite 1272-1275","issue":"4","pages":"1272-1275","year":"2014"},"pubHistory":["1.1879 -"],"language":["eng"],"corporate":[{"display":"American Chemical Society","roleDisplay":"VerfasserIn","role":"aut"}],"recId":"268132836","note":["Gesehen am 25.08.2020"],"disp":"American Chemical SocietyJournal of the American Chemical Society","type":{"media":"Online-Ressource","bibl":"periodical"},"id":{"issn":["1520-5126"],"zdb":["1472210-0"],"eki":["268132836"]},"origin":[{"publisherPlace":"Washington, DC ; Washington, DC","dateIssuedDisp":"1879-","publisher":"ACS Publications ; American Chemical Society","dateIssuedKey":"1879"}],"name":{"displayForm":["Ed.: Allen J. Bard [u.a.]"]}}]} | ||
| SRT | |a QUJIANPINGENANTIOAND1420 | ||