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CO extrusion in homogeneous gold catalysis: reactivity of gold acyl species generated through water addition to gold vinylidenes

Herein, we describe a new gold-catalyzed decarbonylative indene synthesis. Synergistic σ,π-activation of diyne substrates leads to gold vinylidene intermediates, which upon addition of water are transformed into gold acyl species, a type of organogold compound hitherto only scarcely reported. The la...

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Hauptverfasser: Bucher, Janina (VerfasserIn) , Stößer, Tim (VerfasserIn) , Rudolph, Matthias (VerfasserIn) , Rominger, Frank (VerfasserIn) , Hashmi, A. Stephen K. (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: December 15, 2014
In: Angewandte Chemie. International edition
Year: 2015, Jahrgang: 54, Heft: 5, Pages: 1666-1670
ISSN:1521-3773
DOI:10.1002/anie.201409859
Online-Zugang:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.201409859
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201409859
Volltext
Verfasserangaben:Janina Bucher, Tim Stößer, Matthias Rudolph, Frank Rominger, and A. Stephen K. Hashmi

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