Unexpected reactivity patterns of Ruthenium alkylidenes with N-phosphino-functionalized N-heterocyclic carbene ligands (NHCPs)
N-phosphino-functionalized N-heterocyclic carbene (NHCP) ligands have been evaluated as potential supporting ligands in ruthenium-catalyzed olefin metathesis. Initial density functional theory (DFT) calculations suggested that these NHCP ligands may allow access to neutral 14 valence electron (VE) s...
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
17 November 2014
|
| In: |
Organometallics
Year: 2014, Jahrgang: 33, Heft: 23, Pages: 6754-6759$z6 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om5005429 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/om5005429
|
| Verfasserangaben: | Christopher C. Brown, Philipp N. Plessow, Frank Rominger, Michael Limbach, and Peter Hofmann |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1735724971 | ||
| 003 | DE-627 | ||
| 005 | 20220818230610.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 201016s2014 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/om5005429 |2 doi | |
| 035 | |a (DE-627)1735724971 | ||
| 035 | |a (DE-599)KXP1735724971 | ||
| 035 | |a (OCoLC)1341371271 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Brown, Christopher |e VerfasserIn |0 (DE-588)121119633X |0 (DE-627)1699026203 |4 aut | |
| 245 | 1 | 0 | |a Unexpected reactivity patterns of Ruthenium alkylidenes with N-phosphino-functionalized N-heterocyclic carbene ligands (NHCPs) |c Christopher C. Brown, Philipp N. Plessow, Frank Rominger, Michael Limbach, and Peter Hofmann |
| 264 | 1 | |c 17 November 2014 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 16.10.2020 | ||
| 520 | |a N-phosphino-functionalized N-heterocyclic carbene (NHCP) ligands have been evaluated as potential supporting ligands in ruthenium-catalyzed olefin metathesis. Initial density functional theory (DFT) calculations suggested that these NHCP ligands may allow access to neutral 14 valence electron (VE) species—equivalents of the active 14 VE species formed by phosphine dissociation from Grubbs II precatalysts—via facile decoordination of the NHCP phosphino donor of the strained four-membered [RuPNC] chelate systems. Their attempted synthesis from NHCPs and Grubbs-type Ru carbenes revealed addition of an NHCP donor atom (P or C) to the alkylidene fragment, forming a new C-P or C-C bond in five-membered chelate structures. DFT investigations showed that these reactions are controlled kinetically and must not be neglected as important possible deactivation routes in olefin metathesis. | ||
| 700 | 1 | |a Rominger, Frank |d 1964- |e VerfasserIn |0 (DE-588)1019978228 |0 (DE-627)691067821 |0 (DE-576)359202756 |4 aut | |
| 700 | 1 | |a Hofmann, Peter |d 1947-2015 |e VerfasserIn |0 (DE-588)1058186078 |0 (DE-627)796524513 |0 (DE-576)414198107 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Organometallics |d Washington, DC : ACS Publ., 1982 |g 33(2014), 23, Seite 6754-6759$z6 |h Online-Ressource |w (DE-627)320453111 |w (DE-600)2006302-7 |w (DE-576)09088941X |x 1520-6041 |7 nnas |a Unexpected reactivity patterns of Ruthenium alkylidenes with N-phosphino-functionalized N-heterocyclic carbene ligands (NHCPs) |
| 773 | 1 | 8 | |g volume:33 |g year:2014 |g number:23 |g pages:6754-6759$z6 |a Unexpected reactivity patterns of Ruthenium alkylidenes with N-phosphino-functionalized N-heterocyclic carbene ligands (NHCPs) |
| 856 | 4 | 0 | |u https://doi.org/10.1021/om5005429 |x Verlag |x Resolving-System |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20201016 | ||
| 993 | |a Article | ||
| 994 | |a 2014 | ||
| 998 | |g 1058186078 |a Hofmann, Peter |m 1058186078:Hofmann, Peter |d 120000 |d 120100 |e 120000PH1058186078 |e 120100PH1058186078 |k 0/120000/ |k 1/120000/120100/ |p 5 |y j | ||
| 998 | |g 1019978228 |a Rominger, Frank |m 1019978228:Rominger, Frank |d 120000 |d 120100 |e 120000PR1019978228 |e 120100PR1019978228 |k 0/120000/ |k 1/120000/120100/ |p 3 | ||
| 998 | |g 121119633X |a Brown, Christopher |m 121119633X:Brown, Christopher |d 120000 |d 120100 |e 120000PB121119633X |e 120100PB121119633X |k 0/120000/ |k 1/120000/120100/ |p 1 |x j | ||
| 999 | |a KXP-PPN1735724971 |e 3780533154 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"person":[{"given":"Christopher","role":"aut","display":"Brown, Christopher","family":"Brown"},{"display":"Rominger, Frank","family":"Rominger","role":"aut","given":"Frank"},{"display":"Hofmann, Peter","family":"Hofmann","role":"aut","given":"Peter"}],"language":["eng"],"title":[{"title":"Unexpected reactivity patterns of Ruthenium alkylidenes with N-phosphino-functionalized N-heterocyclic carbene ligands (NHCPs)","title_sort":"Unexpected reactivity patterns of Ruthenium alkylidenes with N-phosphino-functionalized N-heterocyclic carbene ligands (NHCPs)"}],"note":["Gesehen am 16.10.2020"],"origin":[{"dateIssuedDisp":"17 November 2014","dateIssuedKey":"2014"}],"type":{"bibl":"article-journal","media":"Online-Ressource"},"recId":"1735724971","name":{"displayForm":["Christopher C. Brown, Philipp N. Plessow, Frank Rominger, Michael Limbach, and Peter Hofmann"]},"id":{"eki":["1735724971"],"doi":["10.1021/om5005429"]},"relHost":[{"recId":"320453111","pubHistory":["1.1982 -"],"physDesc":[{"extent":"Online-Ressource"}],"name":{"displayForm":["American Chemical Society"]},"id":{"issn":["1520-6041"],"eki":["320453111"],"zdb":["2006302-7"]},"disp":"Unexpected reactivity patterns of Ruthenium alkylidenes with N-phosphino-functionalized N-heterocyclic carbene ligands (NHCPs)Organometallics","language":["eng"],"part":{"year":"2014","issue":"23","pages":"6754-6759$z6","text":"33(2014), 23, Seite 6754-6759$z6","volume":"33"},"origin":[{"dateIssuedDisp":"1982-","publisherPlace":"Washington, DC","publisher":"ACS Publ.","dateIssuedKey":"1982"}],"note":["Gesehen am 22.03.23"],"type":{"media":"Online-Ressource","bibl":"periodical"},"title":[{"title":"Organometallics","subtitle":"web edition","title_sort":"Organometallics"}]}]} | ||
| SRT | |a BROWNCHRISUNEXPECTED1720 | ||