Carbon-rich cycles with two and more 1,3-butadiyne units: syntheses, structures and reactivities
This chapter contains sections titled: Introduction Syntheses 1,3-Butadiyne Moieties as Spacers and Framework Reactivity Base-induced Prototropic Rearrangements Elimination Reactions Reductions of Cyclic 1,3-Butadiynes Acid-induced Transannular Reactions Spectroscopic and Structural Investigations S...
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| Main Authors: | , |
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| Format: | Chapter/Article |
| Language: | English |
| Published: |
06 February 2006
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| In: |
Carbon-rich compounds
Year: 2006, Pages: 295-333 |
| DOI: | 10.1002/3527607994.ch7 |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/3527607994.ch7 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/3527607994.ch7 
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| Author Notes: | Rolf Gleiter, Daniel B. Werz |
| Summary: | This chapter contains sections titled: Introduction Syntheses 1,3-Butadiyne Moieties as Spacers and Framework Reactivity Base-induced Prototropic Rearrangements Elimination Reactions Reductions of Cyclic 1,3-Butadiynes Acid-induced Transannular Reactions Spectroscopic and Structural Investigations Structural Investigations NMR Spectroscopic Investigations Photoelectron and Electron Absorption Spectra of Cyclic 1,3-Diynes Concluding Remarks and Outlook Experimental: Selected Procedures General Procedure for the Preparation of N,N'-Dialkyl-1,8-diazacyclotetradeca-3,5,10,12-tetraynes (27a-e) General Procedure for the Cadiot-Chodkiewicz Coupling During the Syntheses of Azacyclotetraynes 10(n) General Procedure for the Preparation of the Tetrachalcogenacyclo-tetraynes 29(n) and 33(n) and Hexachalcogenacyclohexaynes 34(n) and 35(n) General Procedures for the Preparation of Hexadiyne-bridged Macrobicycles Alternative A Alternative B |
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| Item Description: | Gesehen am 21.10.2020 |
| Physical Description: | Online Resource |
| ISBN: | 3527312242 3527607994 9783527607990 3527607242 9783527607242 |
| DOI: | 10.1002/3527607994.ch7 |