Carbon-rich cycles with two and more 1,3-butadiyne units: syntheses, structures and reactivities

This chapter contains sections titled: Introduction Syntheses 1,3-Butadiyne Moieties as Spacers and Framework Reactivity Base-induced Prototropic Rearrangements Elimination Reactions Reductions of Cyclic 1,3-Butadiynes Acid-induced Transannular Reactions Spectroscopic and Structural Investigations S...

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Hauptverfasser: Gleiter, Rolf (VerfasserIn) , Werz, Daniel B. (VerfasserIn)
Dokumenttyp: Kapitel/Artikel
Sprache:Englisch
Veröffentlicht: 06 February 2006
In: Carbon-rich compounds
Year: 2006, Pages: 295-333
DOI:10.1002/3527607994.ch7
Online-Zugang:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/3527607994.ch7
Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/3527607994.ch7
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Verfasserangaben:Rolf Gleiter, Daniel B. Werz
Beschreibung
Zusammenfassung:This chapter contains sections titled: Introduction Syntheses 1,3-Butadiyne Moieties as Spacers and Framework Reactivity Base-induced Prototropic Rearrangements Elimination Reactions Reductions of Cyclic 1,3-Butadiynes Acid-induced Transannular Reactions Spectroscopic and Structural Investigations Structural Investigations NMR Spectroscopic Investigations Photoelectron and Electron Absorption Spectra of Cyclic 1,3-Diynes Concluding Remarks and Outlook Experimental: Selected Procedures General Procedure for the Preparation of N,N'-Dialkyl-1,8-diazacyclotetradeca-3,5,10,12-tetraynes (27a-e) General Procedure for the Cadiot-Chodkiewicz Coupling During the Syntheses of Azacyclotetraynes 10(n) General Procedure for the Preparation of the Tetrachalcogenacyclo-tetraynes 29(n) and 33(n) and Hexachalcogenacyclohexaynes 34(n) and 35(n) General Procedures for the Preparation of Hexadiyne-bridged Macrobicycles Alternative A Alternative B
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Beschreibung:Online Resource
ISBN:3527312242
3527607994
9783527607990
3527607242
9783527607242
DOI:10.1002/3527607994.ch7