Nickel-catalyzed direct carboxylation of olefins with CO2: one-pot synthesis of α,β-unsaturated carboxylic acid salts
The nickel-catalyzed direct carboxylation of alkenes with the cheap and abundantly available C1 building block carbon dioxide (CO2) in the presence of a base has been achieved. The one-pot reaction allows for the direct and selective synthesis of a wide range of α,β-unsaturated carboxylates (TON>...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
30 October 2014
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| In: |
Chemistry - a European journal
Year: 2014, Volume: 20, Issue: 51, Pages: 16858-16862 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201405528 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201405528 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201405528 
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| Author Notes: | Núria Huguet, Ivana Jevtovikj, Alvaro Gordillo, Michael L. Lejkowski, Ronald Lindner, Miriam Bru, Andrey Y. Khalimon, Frank Rominger, Stephan A. Schunk, Peter Hofmann, and Michael Limbach |
| Summary: | The nickel-catalyzed direct carboxylation of alkenes with the cheap and abundantly available C1 building block carbon dioxide (CO2) in the presence of a base has been achieved. The one-pot reaction allows for the direct and selective synthesis of a wide range of α,β-unsaturated carboxylates (TON>100, TOF up to 6 h−1, TON=turnover number, TOF=turnover frequency). Thus, it is possible, in one step, to synthesize sodium acrylate from ethylene, CO2, and a sodium salt. Acrylates are industrially important products, the synthesis of which has hitherto required multiple steps. |
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| Item Description: | Gesehen am 21.10.2020 Im Titel ist die Zahl 2 tiefgestellt |
| Physical Description: | Online Resource |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201405528 |