Nickel-catalyzed direct carboxylation of olefins with CO2: one-pot synthesis of α,β-unsaturated carboxylic acid salts
The nickel-catalyzed direct carboxylation of alkenes with the cheap and abundantly available C1 building block carbon dioxide (CO2) in the presence of a base has been achieved. The one-pot reaction allows for the direct and selective synthesis of a wide range of α,β-unsaturated carboxylates (TON>...
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
30 October 2014
|
| In: |
Chemistry - a European journal
Year: 2014, Jahrgang: 20, Heft: 51, Pages: 16858-16862 |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201405528 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/chem.201405528 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201405528 
|
| Verfasserangaben: | Núria Huguet, Ivana Jevtovikj, Alvaro Gordillo, Michael L. Lejkowski, Ronald Lindner, Miriam Bru, Andrey Y. Khalimon, Frank Rominger, Stephan A. Schunk, Peter Hofmann, and Michael Limbach |
| Zusammenfassung: | The nickel-catalyzed direct carboxylation of alkenes with the cheap and abundantly available C1 building block carbon dioxide (CO2) in the presence of a base has been achieved. The one-pot reaction allows for the direct and selective synthesis of a wide range of α,β-unsaturated carboxylates (TON>100, TOF up to 6 h−1, TON=turnover number, TOF=turnover frequency). Thus, it is possible, in one step, to synthesize sodium acrylate from ethylene, CO2, and a sodium salt. Acrylates are industrially important products, the synthesis of which has hitherto required multiple steps. |
|---|---|
| Beschreibung: | Gesehen am 21.10.2020 Im Titel ist die Zahl 2 tiefgestellt |
| Beschreibung: | Online Resource |
| ISSN: | 1521-3765 |
| DOI: | 10.1002/chem.201405528 |