A stepwise degradation of sterically hindered CpCo-cyclobutadiene complexes

Sterically hindered CpCo stabilized cyclobutadiene complexes 4 were oxidized by ceric ammonium nitrate to yield the dinitratocobalt complexes 5. The thermolysis of 5a and the reaction of 5a with tert-butyl isocyanide as well as NaBH4 is reported.

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Bibliographic Details
Main Authors: Schaefer, Carsten (Author) , Gleiter, Rolf (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: 9th November 2004
In: Dalton transactions
Year: 2004, Issue: 24, Pages: 4146-4151
ISSN:1477-9234
DOI:10.1039/B412167H
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1039/B412167H
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2004/dt/b412167h
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Author Notes:Carsten Schaefer, Rolf Gleiter and Frank Rominger

MARC

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