Endohedral metallocenophanes of rhodium and cobalt
The synthesis of seven endohedral metallocenophanes of rhodium (7b, 8b) and cobalt (1d−h) with a cyclopentadienyl unit as one of the π-systems and a cyclobutadiene or cyclopentadienone unit as the second π-system is described, including the synthesis of the unsubstituted parent compound of the [CpCo...
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| Main Authors: | , , , , |
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| Format: | Article (Journal) Festschrift |
| Language: | English |
| Published: |
07 April 2005
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| In: |
European journal of inorganic chemistry
Year: 2005, Issue: 7, Pages: 1274-1281 |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.200400851 |
| Subjects: | |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejic.200400851 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejic.200400851 
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| Author Notes: | Carsten Schaefer, Gerald Scholz, Rolf Gleiter, Thomas Oeser, and Frank Rominger |
| Summary: | The synthesis of seven endohedral metallocenophanes of rhodium (7b, 8b) and cobalt (1d−h) with a cyclopentadienyl unit as one of the π-systems and a cyclobutadiene or cyclopentadienone unit as the second π-system is described, including the synthesis of the unsubstituted parent compound of the [CpCo(cbd)]-derived endohedral phanes, [3.3]-η5-(1,1',3,3')-cyclopentadienyl-η4-(cyclobutadienophane)co-balt(I) (1h). This compound could be obtained by deprotection of the corresponding trimethylsilyl-substituted endohedral phane 1g. The X-ray structures of 7b, 1e, 1g and 1h could be obtained. This paper compares their structural properties to the complexes reported in previous short communications. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005) |
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| Item Description: | Dedicated to Professor Paul von Ragué Schleyer on the occasion of his 75th birthday Gesehen am 23.10.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1099-0682 |
| DOI: | 10.1002/ejic.200400851 |