Reactivity of the [η2-bis(tert-butylsulfonyl)acetylene](carbonyl)(η5-cyclopentadienyl)cobalt complex towards electron-rich and -poor ccetylenes

The electron-rich aminoacetylenes Et2NC2R (2a-c, R = SPh, PPh2, and Ph, respectively) react smoothly with [η2-bis(tert-butylsulfonyl)acetylene](carbonyl)(η5-cyclopentadienyl)co-balt (1) to form the donor-acceptor stabilized (η4-cyclobutadiene)cobalt complexes 3a-c in good yields. However, treatment...

Full description

Saved in:
Bibliographic Details
Main Authors: Goswami, Avijit (Author) , Stäb, Tobias (Author) , Rominger, Frank (Author) , Gleiter, Rolf (Author) , Siebert, Walter (Author)
Format: Article (Journal) Festschrift
Language:English
Published: August 24, 2005
In: European journal of inorganic chemistry
Year: 2005, Issue: 20, Pages: 4086-4089
ISSN:1099-0682
DOI:10.1002/ejic.200500308
Subjects:
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejic.200500308
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejic.200500308
Get full text
Author Notes:Avijit Goswami, Tobias H. Staeb, Frank Rominger, Rolf Gleiter, and Walter Siebert
Search Result 1

The role of [η2-bis(tert-butylsulfonyl)acetylene](carbonyl)(η5-cyclopentadienyl)cobalt(I) as an intermediate in the alkyne dimerisation by Stäb, Tobias (Author) , Chávez, Jorge A. (Author) , Gleiter, Rolf (Author) , Nuber, Bernhard (Author) ,


Get full text
Article (Journal) Festschrift Online Resource
Search Result 2

(η5-Cyclopentadienyl)(η2-bis(tert-butylsulfonyl)acetylene)(carbonyl)cobalt: an electrophilic reagent to yield CpCo-stabilized cyclobutadiene derivatives by Benisch, Christoph (Author) , Gleiter, Rolf (Author) , Stäb, Tobias (Author) , Nuber, Bernhard (Author) , Oeser, Thomas (Author) , Pritzkow, Hans (Author) , Rominger, Frank (Author) ,


Get full text
Article (Journal) Online Resource
Search Result 3

Reactions of 1,8-diheterocyclotetradeca-4,11-diynes with (η4-cycloocta-1,5-diene)(η5-cyclopentadienyl)cobalt by Wolfart, Volker (Author) , Ramming, Matthias (Author) , Gleiter, Rolf (Author) , Nuber, Bernhard (Author) , Pritzkow, Hans (Author) , Rominger, Frank (Author) ,


Get full text
Article (Journal) Online Resource