Donor-acceptor-substituted phenylacetylene macrocycles with threefold symmetry
A stepwise synthesis of the donor-acceptor-substituted macrocycle 5,21,37-tris(diethylamino)-13,29,45-trinitro[2.2.2.2.2.2]metacyclophane-1,9,17,25,33,42-hexayne (1a) from 3,5-bis(3-iodo-5-nitrophenylethynyl)-N,N-diethylaniline (11) and 3,5-bis([3-diethylamino-5-ethynylphenyl]ethynyl)nitrobenzene (1...
Gespeichert in:
| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) Festschrift |
| Sprache: | Englisch |
| Veröffentlicht: |
04 April 2005
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| In: |
European journal of organic chemistry
Year: 2005, Heft: 7, Pages: 1283-1292 |
| ISSN: | 1099-0690 |
| DOI: | 10.1002/ejoc.200400603 |
| Schlagworte: | |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejoc.200400603 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.200400603 |
| Verfasserangaben: | Boris Traber, Thomas Oeser, and Rolf Gleiter |
MARC
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| 500 | |a Dedicated to Professor Franz Effenberger on the occasion of his 75th birthday | ||
| 500 | |a Gesehen am 22.10.2020 | ||
| 520 | |a A stepwise synthesis of the donor-acceptor-substituted macrocycle 5,21,37-tris(diethylamino)-13,29,45-trinitro[2.2.2.2.2.2]metacyclophane-1,9,17,25,33,42-hexayne (1a) from 3,5-bis(3-iodo-5-nitrophenylethynyl)-N,N-diethylaniline (11) and 3,5-bis([3-diethylamino-5-ethynylphenyl]ethynyl)nitrobenzene (12) failed, mostly due to the low solubility of 1a. The synthesis of the 5,21,37-tris(N,N-di-n-hexylamino) congener of 1a, 1b, was achieved in a one-pot reaction from 1,3-diiodo-5-nitrobenzene (3) and 3,5-diethynyl-N,N-di(n-hexyl)aniline (16) in 23?% yield. X-ray investigations on 1b revealed a planar π ring system with an inner diameter of 10 Å. Despite a high absorbance of 1b at 300 nm, no measurable NLO activity was found. | ||
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| 650 | 4 | |a Macrocycles | |
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