Buchumschlag

Preparation and structures of cyclic tetrathiadienes and tetrathiaenynes

Through the use of diisobutylaluminium hydride (DIBAH) we were able to reduce selectively the triple bond(s) of the following cyclic diynes: 1,4,7,10-tetrathiacyclodeca-2,8-diyne (1), 1,4,8,11-tetrathiacyclotetradeca-2,9-diyne (2), 1,4,9,12-tetrathiacyclohexadeca-2,10-diyne (3), 1,4,10,13-tetrathiac...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Stäb, Tobias (VerfasserIn) , Gleiter, Rolf (VerfasserIn) , Rominger, Frank (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 24 July 2002
In: European journal of organic chemistry
Year: 2002, Heft: 16, Pages: 2815-2822
ISSN:1099-0690
DOI:10.1002/1099-0690(200208)2002:16<2815::AID-EJOC2815>3.0.CO;2-9
Online-Zugang:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/1099-0690(200208)2002:16<2815::AID-EJOC2815>3.0.CO;2-9
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/1099-0690%28200208%292002%3A16%3C2815%3A%3AAID-EJOC2815%3E3.0.CO%3B2-9
Volltext
Verfasserangaben:Tobias H. Staeb, Rolf Gleiter, and Frank Rominger

MARC

LEADER 00000caa a2200000 c 4500
001 173667451X
003 DE-627
005 20220819002134.0
007 cr uuu---uuuuu
008 201027s2002 xx |||||o 00| ||eng c
024 7 |a 10.1002/1099-0690(200208)2002:16<2815::AID-EJOC2815>3.0.CO;2-9  |2 doi 
035 |a (DE-627)173667451X 
035 |a (DE-599)KXP173667451X 
035 |a (OCoLC)1341373348 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Stäb, Tobias  |e VerfasserIn  |0 (DE-588)1220117412  |0 (DE-627)1736487264  |4 aut 
245 1 0 |a Preparation and structures of cyclic tetrathiadienes and tetrathiaenynes  |c Tobias H. Staeb, Rolf Gleiter, and Frank Rominger 
264 1 |c 24 July 2002 
300 |a 8 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Gesehen am 27.10.2020 
520 |a Through the use of diisobutylaluminium hydride (DIBAH) we were able to reduce selectively the triple bond(s) of the following cyclic diynes: 1,4,7,10-tetrathiacyclodeca-2,8-diyne (1), 1,4,8,11-tetrathiacyclotetradeca-2,9-diyne (2), 1,4,9,12-tetrathiacyclohexadeca-2,10-diyne (3), 1,4,10,13-tetrathiacyclooctadeca-2,11-diyne (4), 1,4,11,14-tetrathiacycloeicosa-2,12-diyne (5), 1,4,8,11-tetrathiacycloheptadeca-2,9-diyne (6), and 7,16-dioxa-1,4,10,13-tetrathiacyclooctadeca-2,11-diyne (7). The resulting cyclic enynes 8−14 and cyclic dienes 15−20 were isolated and characterized by their analytical data. In the cases of 8, 10, 11, 14, and 15−20 we were able to isolate single crystals, which were investigated by X-ray diffraction. For all molecular structures we found stair-like conformations. These shapes of the molecules were traced back to the zigzag arrangements of the hydrocarbon chains and the rigid building units (S−CH=CH−S) and/or (S−C≡C−S). In the solid-state forms of 11, 16, 17, and 19 we encountered columnar structures caused by close contacts between sulfur centers of neighboring rings. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002) 
650 4 |a Alkynes 
650 4 |a Columnar structures 
650 4 |a Hydrogenation 
650 4 |a Macrocycles 
650 4 |a Sulfur heterocycles 
700 1 |a Gleiter, Rolf  |d 1936-  |e VerfasserIn  |0 (DE-588)1035293870  |0 (DE-627)747237077  |0 (DE-576)382908473  |4 aut 
700 1 |a Rominger, Frank  |d 1964-  |e VerfasserIn  |0 (DE-588)1019978228  |0 (DE-627)691067821  |0 (DE-576)359202756  |4 aut 
773 0 8 |i Enthalten in  |t European journal of organic chemistry  |d Weinheim : Wiley-VCH Verl., 1998  |g (2002), 16, Seite 2815-2822  |h Online-Ressource  |w (DE-627)269534539  |w (DE-600)1475010-7  |w (DE-576)07788468X  |x 1099-0690  |7 nnas  |a Preparation and structures of cyclic tetrathiadienes and tetrathiaenynes 
773 1 8 |g year:2002  |g number:16  |g pages:2815-2822  |g extent:8  |a Preparation and structures of cyclic tetrathiadienes and tetrathiaenynes 
856 4 0 |u https://doi.org/10.1002/1099-0690(200208)2002:16<2815::AID-EJOC2815>3.0.CO;2-9  |x Resolving-System  |x Verlag  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/1099-0690%28200208%292002%3A16%3C2815%3A%3AAID-EJOC2815%3E3.0.CO%3B2-9  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20201027 
993 |a Article 
994 |a 2002 
998 |g 1019978228  |a Rominger, Frank  |m 1019978228:Rominger, Frank  |d 120000  |d 120100  |e 120000PR1019978228  |e 120100PR1019978228  |k 0/120000/  |k 1/120000/120100/  |p 3  |y j 
998 |g 1035293870  |a Gleiter, Rolf  |m 1035293870:Gleiter, Rolf  |d 120000  |d 120100  |e 120000PG1035293870  |e 120100PG1035293870  |k 0/120000/  |k 1/120000/120100/  |p 2 
998 |g 1220117412  |a Stäb, Tobias  |m 1220117412:Stäb, Tobias  |d 120000  |d 120100  |e 120000PS1220117412  |e 120100PS1220117412  |k 0/120000/  |k 1/120000/120100/  |p 1  |x j 
999 |a KXP-PPN173667451X  |e 3786723567 
BIB |a Y 
SER |a journal 
JSO |a {"language":["eng"],"type":{"bibl":"article-journal","media":"Online-Ressource"},"note":["Gesehen am 27.10.2020"],"origin":[{"dateIssuedDisp":"24 July 2002","dateIssuedKey":"2002"}],"title":[{"title_sort":"Preparation and structures of cyclic tetrathiadienes and tetrathiaenynes","title":"Preparation and structures of cyclic tetrathiadienes and tetrathiaenynes"}],"person":[{"role":"aut","given":"Tobias","display":"Stäb, Tobias","family":"Stäb"},{"display":"Gleiter, Rolf","family":"Gleiter","role":"aut","given":"Rolf"},{"family":"Rominger","display":"Rominger, Frank","given":"Frank","role":"aut"}],"id":{"doi":["10.1002/1099-0690(200208)2002:16<2815::AID-EJOC2815>3.0.CO;2-9"],"eki":["173667451X"]},"relHost":[{"pubHistory":["1998 -"],"recId":"269534539","physDesc":[{"extent":"Online-Ressource"}],"id":{"issn":["1099-0690"],"eki":["269534539"],"zdb":["1475010-7"],"doi":["10.1002/(ISSN)1099-0690"]},"disp":"Preparation and structures of cyclic tetrathiadienes and tetrathiaenynesEuropean journal of organic chemistry","language":["eng"],"title":[{"title_sort":"European journal of organic chemistry","title":"European journal of organic chemistry"}],"note":["Gesehen am 21.01.04"],"origin":[{"publisherPlace":"Weinheim","dateIssuedDisp":"1998-","publisher":"Wiley-VCH Verl.","dateIssuedKey":"1998"}],"type":{"bibl":"periodical","media":"Online-Ressource"},"part":{"extent":"8","text":"(2002), 16, Seite 2815-2822","pages":"2815-2822","issue":"16","year":"2002"}}],"recId":"173667451X","physDesc":[{"extent":"8 S."}],"name":{"displayForm":["Tobias H. Staeb, Rolf Gleiter, and Frank Rominger"]}} 
SRT |a STAEBTOBIAPREPARATIO2420 

Ähnliche Einträge