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Selenium- and tellurium-substituted cyclopropenones and their facile ring-opening with methanol

Treatment of donor-substituted acetylenes (X−C≡C−X, with X = R−Se, R−Te) with sodium trichloroacetate, followed by hydrolysis, yielded the corresponding cyclopropenones. Their structures could be elucidated by X-ray analysis, and indicated significant overlap between the p-type lone pairs on the cha...

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Bibliographic Details
Main Authors: Werz, Daniel B. (Author) , Gleiter, Rolf (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: 2003
In: European journal of organic chemistry
Year: 2002, Issue: 1, Pages: 151-154
ISSN:1099-0690
DOI:10.1002/1099-0690(200301)2003:1<151::AID-EJOC151>3.0.CO;2-7
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/1099-0690(200301)2003:1<151::AID-EJOC151>3.0.CO;2-7
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/1099-0690%28200301%292003%3A1%3C151%3A%3AAID-EJOC151%3E3.0.CO%3B2-7
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Author Notes:Daniel B. Werz, Rolf Gleiter, and Frank Rominger

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