Inside protonation of 1,8-diazabicyclo[6.6.n]alka-4,11-diynes

Protonation of 1,8-diazabicyclo[6.6.3]heptadeca-4,11-diyne (4a), 1,8-diazabicyclo[6.6.4]octa-deca-4,11-diyne (4b), 1,8-diazabicyclo[6.6.5]nonadeca-4,11-diyne (4c), and 1,8-diazabicyclo[6.6.6]eicosa-4,11-diyne (4d) was achieved by treatment of 4a−4d with strong acids. Monoprotonation products were is...

Full description

Saved in:
Bibliographic Details
Main Authors: Balalaie, Saeed (Author) , Kunze, Andreas (Author) , Gleiter, Rolf (Author) , Rominger, Frank (Author) , Geis, Sibylle (Author) , Oeser, Thomas (Author)
Format: Article (Journal)
Language:English
Published: 12 August 2003
In: European journal of organic chemistry
Year: 2003, Issue: 17, Pages: 3378-3381
ISSN:1099-0690
DOI:10.1002/ejoc.200300235
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejoc.200300235
Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.200300235
Get full text
Author Notes:Saeed Balalaie, Andreas Kunze, Rolf Gleiter, Frank Rominger, Sibylle Geis, and Thomas Oeser

MARC

LEADER 00000caa a2200000 c 4500
001 1736687476
003 DE-627
005 20220819002420.0
007 cr uuu---uuuuu
008 201027s2003 xx |||||o 00| ||eng c
024 7 |a 10.1002/ejoc.200300235  |2 doi 
035 |a (DE-627)1736687476 
035 |a (DE-599)KXP1736687476 
035 |a (OCoLC)1341374864 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Balalaie, Saeed  |e VerfasserIn  |0 (DE-588)1166290956  |0 (DE-627)1030296421  |0 (DE-576)510714331  |4 aut 
245 1 0 |a Inside protonation of 1,8-diazabicyclo[6.6.n]alka-4,11-diynes  |c Saeed Balalaie, Andreas Kunze, Rolf Gleiter, Frank Rominger, Sibylle Geis, and Thomas Oeser 
264 1 |c 12 August 2003 
300 |a 4 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Gesehen am 27.10.2020 
520 |a Protonation of 1,8-diazabicyclo[6.6.3]heptadeca-4,11-diyne (4a), 1,8-diazabicyclo[6.6.4]octa-deca-4,11-diyne (4b), 1,8-diazabicyclo[6.6.5]nonadeca-4,11-diyne (4c), and 1,8-diazabicyclo[6.6.6]eicosa-4,11-diyne (4d) was achieved by treatment of 4a−4d with strong acids. Monoprotonation products were isolated in all cases, while for 4b and 4c diprotonation products were also obtained. X-ray investigations show inside protonation for the mono- and diprotonation products. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) 
650 4 |a Alkynes 
650 4 |a Medium-ring compounds 
650 4 |a Protonation 
700 1 |a Kunze, Andreas  |e VerfasserIn  |0 (DE-588)1141181061  |0 (DE-627)898933048  |0 (DE-576)494232358  |4 aut 
700 1 |a Gleiter, Rolf  |d 1936-  |e VerfasserIn  |0 (DE-588)1035293870  |0 (DE-627)747237077  |0 (DE-576)382908473  |4 aut 
700 1 |a Rominger, Frank  |d 1964-  |e VerfasserIn  |0 (DE-588)1019978228  |0 (DE-627)691067821  |0 (DE-576)359202756  |4 aut 
700 1 |a Geis, Sibylle  |e VerfasserIn  |4 aut 
700 1 |a Oeser, Thomas  |e VerfasserIn  |0 (DE-588)1025249038  |0 (DE-627)721919715  |0 (DE-576)170725553  |4 aut 
773 0 8 |i Enthalten in  |t European journal of organic chemistry  |d Weinheim : Wiley-VCH Verl., 1998  |g (2003), 17, Seite 3378-3381  |h Online-Ressource  |w (DE-627)269534539  |w (DE-600)1475010-7  |w (DE-576)07788468X  |x 1099-0690  |7 nnas  |a Inside protonation of 1,8-diazabicyclo[6.6.n]alka-4,11-diynes 
773 1 8 |g year:2003  |g number:17  |g pages:3378-3381  |g extent:4  |a Inside protonation of 1,8-diazabicyclo[6.6.n]alka-4,11-diynes 
856 4 0 |u https://doi.org/10.1002/ejoc.200300235  |x Resolving-System  |x Verlag  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.200300235  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20201027 
993 |a Article 
994 |a 2003 
998 |g 1025249038  |a Oeser, Thomas  |m 1025249038:Oeser, Thomas  |d 120000  |d 120100  |e 120000PO1025249038  |e 120100PO1025249038  |k 0/120000/  |k 1/120000/120100/  |p 6  |y j 
998 |g 1019978228  |a Rominger, Frank  |m 1019978228:Rominger, Frank  |d 120000  |d 120100  |e 120000PR1019978228  |e 120100PR1019978228  |k 0/120000/  |k 1/120000/120100/  |p 4 
998 |g 1035293870  |a Gleiter, Rolf  |m 1035293870:Gleiter, Rolf  |d 120000  |d 120100  |e 120000PG1035293870  |e 120100PG1035293870  |k 0/120000/  |k 1/120000/120100/  |p 3 
998 |g 1141181061  |a Kunze, Andreas  |m 1141181061:Kunze, Andreas  |d 120000  |d 120100  |e 120000PK1141181061  |e 120100PK1141181061  |k 0/120000/  |k 1/120000/120100/  |p 2 
999 |a KXP-PPN1736687476  |e 3786766231 
BIB |a Y 
SER |a journal 
JSO |a {"relHost":[{"disp":"Inside protonation of 1,8-diazabicyclo[6.6.n]alka-4,11-diynesEuropean journal of organic chemistry","recId":"269534539","language":["eng"],"type":{"bibl":"periodical","media":"Online-Ressource"},"pubHistory":["1998 -"],"origin":[{"publisherPlace":"Weinheim","dateIssuedKey":"1998","dateIssuedDisp":"1998-","publisher":"Wiley-VCH Verl."}],"title":[{"title":"European journal of organic chemistry","title_sort":"European journal of organic chemistry"}],"part":{"text":"(2003), 17, Seite 3378-3381","extent":"4","year":"2003","pages":"3378-3381","issue":"17"},"id":{"eki":["269534539"],"zdb":["1475010-7"],"doi":["10.1002/(ISSN)1099-0690"],"issn":["1099-0690"]},"physDesc":[{"extent":"Online-Ressource"}],"note":["Gesehen am 21.01.04"]}],"note":["Gesehen am 27.10.2020"],"type":{"media":"Online-Ressource","bibl":"article-journal"},"id":{"eki":["1736687476"],"doi":["10.1002/ejoc.200300235"]},"physDesc":[{"extent":"4 S."}],"language":["eng"],"title":[{"title_sort":"Inside protonation of 1,8-diazabicyclo[6.6.n]alka-4,11-diynes","title":"Inside protonation of 1,8-diazabicyclo[6.6.n]alka-4,11-diynes"}],"recId":"1736687476","name":{"displayForm":["Saeed Balalaie, Andreas Kunze, Rolf Gleiter, Frank Rominger, Sibylle Geis, and Thomas Oeser"]},"origin":[{"dateIssuedDisp":"12 August 2003","dateIssuedKey":"2003"}],"person":[{"family":"Balalaie","display":"Balalaie, Saeed","given":"Saeed","role":"aut"},{"family":"Kunze","given":"Andreas","display":"Kunze, Andreas","role":"aut"},{"display":"Gleiter, Rolf","given":"Rolf","family":"Gleiter","role":"aut"},{"role":"aut","family":"Rominger","display":"Rominger, Frank","given":"Frank"},{"family":"Geis","display":"Geis, Sibylle","given":"Sibylle","role":"aut"},{"family":"Oeser","display":"Oeser, Thomas","given":"Thomas","role":"aut"}]} 
SRT |a BALALAIESAINSIDEPROT1220