Donor-substituted heptaazaphenalene as a nonlinear optically active molecule with multiple charge-transfer transitions
The synthesis of a novel nonlinear optical (NLO) chromophore with threefold symmetry − 2,5,8-tris(diethylamino)-1,3,4,6,7,9,9b-heptaazaphenalene (4) − is reported. Compound 4 was synthesized from 2,5,8-trichloro-1,3,4,6,7,9,9b-heptaazaphenalene (3) through a nucleophilic aromatic substitution, its s...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
13 October 2004
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| In: |
European journal of organic chemistry
Year: 2004, Heft: 21, Pages: 4387-4390 |
| ISSN: | 1099-0690 |
| DOI: | 10.1002/ejoc.200400308 |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/ejoc.200400308 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/ejoc.200400308 
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| Verfasserangaben: | Boris Traber, Thomas Oeser, Rolf Gleiter, Mark Goebel, and Rüdiger Wortmann |
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| 520 | |a The synthesis of a novel nonlinear optical (NLO) chromophore with threefold symmetry − 2,5,8-tris(diethylamino)-1,3,4,6,7,9,9b-heptaazaphenalene (4) − is reported. Compound 4 was synthesized from 2,5,8-trichloro-1,3,4,6,7,9,9b-heptaazaphenalene (3) through a nucleophilic aromatic substitution, its structural assignment was confirmed by X-ray investigations, and its second-order polarisability (β) was determined by hyper Rayleigh scattering (HRS). Compound 4 shows a very high absorbance coefficient in the UV and a remarkably large β value despite its short-wavelength absorption. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004) | ||
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