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Reversible OH-bond activation and amphoterism by metal-ligand cooperativity of calix[4]pyrrolato aluminate

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Most p-block metal amides irreversibly react with metal alkoxides when subjected to alcohols, making reversible transformations with OH-substrates a challenging task. Herein, we describe how the combination of a Lewis acidic square-planar-coordinated aluminum(III) center with metal-ligand cooperativ...

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Main Authors: Sigmund, Lukas M. (Author) , Greb, Lutz (Author)
Format: Article (Journal)
Language:English
Published: 20 Aug 2020
In: Chemical science
Year: 2020, Volume: 11, Issue: 35, Pages: 9611-9616
ISSN:2041-6539
DOI:10.1039/D0SC03602A
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/D0SC03602A
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2020/sc/d0sc03602a
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Author Notes:Lukas M. Sigmund and Lutz Greb
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Nitrogen monoxide and calix[4]pyrrolato aluminate: structural constraint enabled NO dimerization by Kohl, Senta J. (Author) , Sigmund, Lukas M. (Author) , Schmitt, Manuel (Author) , Greb, Lutz (Author) ,


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