Activation of alkynes with B(C6F5)3: boron allylation reagents derived from propargyl esters
Novel allyl boron compounds are readily synthesized via rearrangement reactions between Lewis acidic B(C6F5)3 and propargyl esters. These reactions proceed through an initial cyclization followed by ring-opening and concurrent C6F5-group migration. In the absence of disubstitution adjacent to the es...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2014
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| In: |
Journal of the American Chemical Society
Year: 2013, Jahrgang: 136, Heft: 2, Pages: 777-782 |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/ja4110842 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ja4110842 Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/ja4110842 
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| Verfasserangaben: | Max M. Hansmann, Rebecca L. Melen, Frank Rominger, A. Stephen K. Hashmi, and Douglas W. Stephan |