Growth, characterization, and magnetic properties of a Li(Mn,Ni)PO4 single crystal

LiMn0.95Ni0.05PO4 single crystals have been grown for the first time by the travelling-solvent floating-zone method at low argon pressure. The grown sample exhibits large single crystalline grains as revealed by means of polarization microscopy, X-ray Laue back scattering, and single-crystal X-ray d...

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Hauptverfasser: Wang, Kunpeng (VerfasserIn) , Maljuk, Andrey (VerfasserIn) , Blum, Christian G. F. (VerfasserIn) , Kolb, Thomas (VerfasserIn) , Jähne, Carsten (VerfasserIn) , Neef, Christoph (VerfasserIn) , Grafe, Hans-Joachim (VerfasserIn) , Giebeler, Lars (VerfasserIn) , Wadepohl, Hubert (VerfasserIn) , Meyer, Hans-Peter (VerfasserIn) , Wurmehl, Sabine (VerfasserIn) , Klingeler, Rüdiger (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 2014
In: Journal of crystal growth
Year: 2014, Jahrgang: 386, Pages: 16-21
DOI:10.1016/j.jcrysgro.2013.08.032
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jcrysgro.2013.08.032
Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S0022024813005745
Volltext
Verfasserangaben:Kunpeng Wang, Andrey Maljuk, Christian G. F. Blum, Thomas Kolb, Carsten Jähne, Christoph Neef, Hans-Joachim Grafe, Lars Giebeler, Hubert Wadepohl, Hans-Peter Meyer, Sabine Wurmehl, Rüdiger Klingeler

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520 |a LiMn0.95Ni0.05PO4 single crystals have been grown for the first time by the travelling-solvent floating-zone method at low argon pressure. The grown sample exhibits large single crystalline grains as revealed by means of polarization microscopy, X-ray Laue back scattering, and single-crystal X-ray diffraction. The composition of the crystal was determined by Energy-dispersive X-ray (EDX) spectroscopy. LiMn0.95Ni0.05PO4 orders in an orthorhombic olivine-like structure as expected and phase purity was confirmed by powder X-ray diffraction. An oriented cuboid with size of 2.4×2.5×2.7mm3 along a, b, and c crystalline directions, respectively, was used for anisotropic magnetic measurements. 
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