An alkynyltelluronium iodide and its solid state structure: evidence for p→σ* interactions

The synthesis of the first alkynyltelluronium salt is presented. X-ray investigations of this species reveal a two-dimensional polymeric structure, assembled through various secondary Te⋯Te and Te ⋯I interactions. The structure itself can be rationalized in terms of p→σ* interactions.

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Bibliographic Details
Main Authors: Werz, Daniel B. (Author) , Gleiter, Rolf (Author) , Rominger, Frank (Author)
Format: Article (Journal)
Language:English
Published: 17 January 2004
In: Journal of organometallic chemistry
Year: 2004, Volume: 689, Issue: 3, Pages: 627-630
ISSN:1872-8561
DOI:10.1016/j.jorganchem.2003.11.016
Online Access:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.jorganchem.2003.11.016
Verlag, lizenzpflichtig, Volltext: http://www.sciencedirect.com/science/article/pii/S0022328X03011768
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Author Notes:Daniel B Werz, Rolf Gleiter, Frank Rominger

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