Cover Image

Gold catalysis: AuCl-induced polymerization of styrene and n-butylvinylether

Show other versions (1)

Polymerization of styrene, 4-methoxystyrene, and n-butylvinylether was achieved using simple AuCl as catalyst and AgPF6 as cocatalyst. High molecular weights and low polydispersity indices were obtained. Evidence for a cationic mechanism was obtained by reactions with nucleophiles. The mechanistic s...

Full description

Saved in:
Bibliographic Details
Main Authors: Hashmi, A. Stephen K. (Author) , Schäfer, Sascha (Author) , Göker, Verena (Author) , Eisenbach, Claus D. (Author) , Dirnberger, Klaus (Author) , Zhao-Karger, Zhirong (Author) , Crewdson, Patrick (Author)
Format: Article (Journal)
Language:English
Published: 24 February 2014
In: Australian journal of chemistry
Year: 2014, Volume: 67, Issue: 3, Pages: 500-506
ISSN:1445-0038
DOI:10.1071/CH13562
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1071/CH13562
Verlag, lizenzpflichtig, Volltext: https://www.publish.csiro.au/ch/CH13562
Get full text
Author Notes:A. Stephen K. Hashmi, Sascha Schäfer, Verena Göker, Claus D. Eisenbach, Klaus Dirnberger, Zhirong Zhao-Karger and Patrick Crewdson

MARC

LEADER 00000caa a2200000 c 4500
001 1737449218
003 DE-627
005 20230426153210.0
007 cr uuu---uuuuu
008 201030s2014 xx |||||o 00| ||eng c
024 7 |a 10.1071/CH13562  |2 doi 
035 |a (DE-627)1737449218 
035 |a (DE-599)KXP1737449218 
035 |a (OCoLC)1341375169 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Hashmi, A. Stephen K.  |d 1963-  |e VerfasserIn  |0 (DE-588)101199576X  |0 (DE-627)704823926  |0 (DE-576)169176665  |4 aut 
245 1 0 |a Gold catalysis  |b AuCl-induced polymerization of styrene and n-butylvinylether  |c A. Stephen K. Hashmi, Sascha Schäfer, Verena Göker, Claus D. Eisenbach, Klaus Dirnberger, Zhirong Zhao-Karger and Patrick Crewdson 
264 1 |c 24 February 2014 
300 |a 7 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Gesehen am 30.10.2020 
520 |a Polymerization of styrene, 4-methoxystyrene, and n-butylvinylether was achieved using simple AuCl as catalyst and AgPF6 as cocatalyst. High molecular weights and low polydispersity indices were obtained. Evidence for a cationic mechanism was obtained by reactions with nucleophiles. The mechanistic study also indicates a living polymerization with the gold(i)-alkene complex as the resting species. 
700 1 |a Schäfer, Sascha  |e VerfasserIn  |4 aut 
700 1 |a Göker, Verena  |e VerfasserIn  |0 (DE-588)1059724170  |0 (DE-627)798778997  |0 (DE-576)415781183  |4 aut 
700 1 |a Eisenbach, Claus D.  |e VerfasserIn  |4 aut 
700 1 |a Dirnberger, Klaus  |e VerfasserIn  |4 aut 
700 1 |a Zhao-Karger, Zhirong  |d 1970-  |e VerfasserIn  |0 (DE-588)132760231  |0 (DE-627)526879920  |0 (DE-576)299394786  |4 aut 
700 1 |a Crewdson, Patrick  |e VerfasserIn  |4 aut 
773 0 8 |i Enthalten in  |t Australian journal of chemistry  |d Melbourne : CSIRO, 1948  |g 67(2014), 3, Seite 500-506  |h Online-Ressource  |w (DE-627)268132879  |w (DE-600)1472214-8  |w (DE-576)077608801  |x 1445-0038  |7 nnas  |a Gold catalysis AuCl-induced polymerization of styrene and n-butylvinylether 
773 1 8 |g volume:67  |g year:2014  |g number:3  |g pages:500-506  |g extent:7  |a Gold catalysis AuCl-induced polymerization of styrene and n-butylvinylether 
776 0 8 |i Erscheint auch als  |n Druck-Ausgabe  |t Gold catalysis  |d 2014  |w (DE-627)1640826939  |w (DE-576)415779278 
856 4 0 |u https://doi.org/10.1071/CH13562  |x Verlag  |x Resolving-System  |z lizenzpflichtig  |3 Volltext 
856 4 0 |u https://www.publish.csiro.au/ch/CH13562  |x Verlag  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20201030 
993 |a Article 
994 |a 2014 
998 |g 1059724170  |a Göker, Verena  |m 1059724170:Göker, Verena  |d 120000  |d 120100  |e 120000PG1059724170  |e 120100PG1059724170  |k 0/120000/  |k 1/120000/120100/  |p 3 
998 |g 101199576X  |a Hashmi, A. Stephen K.  |m 101199576X:Hashmi, A. Stephen K.  |d 120000  |d 120100  |e 120000PH101199576X  |e 120100PH101199576X  |k 0/120000/  |k 1/120000/120100/  |p 1  |x j 
999 |a KXP-PPN1737449218  |e 3789536377 
BIB |a Y 
SER |a journal 
JSO |a {"origin":[{"dateIssuedDisp":"24 February 2014","dateIssuedKey":"2014"}],"language":["eng"],"recId":"1737449218","note":["Gesehen am 30.10.2020"],"name":{"displayForm":["A. Stephen K. Hashmi, Sascha Schäfer, Verena Göker, Claus D. Eisenbach, Klaus Dirnberger, Zhirong Zhao-Karger and Patrick Crewdson"]},"type":{"bibl":"article-journal","media":"Online-Ressource"},"relHost":[{"origin":[{"dateIssuedDisp":"1948-","publisher":"CSIRO","dateIssuedKey":"1948","publisherPlace":"Melbourne"}],"recId":"268132879","language":["eng"],"note":["Gesehen am 23.10.2025","Fortsetzung der Druck-Ausgabe"],"name":{"displayForm":["CSIRO Australia ; Australian Academy of Science"]},"pubHistory":["1.1948 -"],"part":{"extent":"7","year":"2014","text":"67(2014), 3, Seite 500-506","volume":"67","pages":"500-506","issue":"3"},"disp":"Gold catalysis AuCl-induced polymerization of styrene and n-butylvinyletherAustralian journal of chemistry","titleAlt":[{"title":"Australian journal of scientific research / A"}],"corporate":[{"role":"isb","display":"Commonwealth Scientific and Industrial Research Organization"}],"physDesc":[{"extent":"Online-Ressource"}],"title":[{"title_sort":"Australian journal of chemistry","title":"Australian journal of chemistry"}],"type":{"media":"Online-Ressource","bibl":"periodical"},"id":{"zdb":["1472214-8"],"issn":["1445-0038"],"eki":["268132879"]}}],"title":[{"title":"Gold catalysis","title_sort":"Gold catalysis","subtitle":"AuCl-induced polymerization of styrene and n-butylvinylether"}],"physDesc":[{"extent":"7 S."}],"id":{"doi":["10.1071/CH13562"],"eki":["1737449218"]},"person":[{"family":"Hashmi","display":"Hashmi, A. Stephen K.","role":"aut","given":"A. Stephen K."},{"given":"Sascha","role":"aut","display":"Schäfer, Sascha","family":"Schäfer"},{"given":"Verena","role":"aut","display":"Göker, Verena","family":"Göker"},{"family":"Eisenbach","display":"Eisenbach, Claus D.","role":"aut","given":"Claus D."},{"family":"Dirnberger","display":"Dirnberger, Klaus","role":"aut","given":"Klaus"},{"given":"Zhirong","role":"aut","display":"Zhao-Karger, Zhirong","family":"Zhao-Karger"},{"given":"Patrick","role":"aut","display":"Crewdson, Patrick","family":"Crewdson"}]} 
SRT |a HASHMIASTEGOLDCATALY2420 

Similar Items