Selective and scalable synthesis of sugar alcohols by homogeneous asymmetric hydrogenation of unprotected ketoses
Sugar alcohols are of great importance for the food industry and are promising building blocks for bio-based polymers. Industrially, they are produced by heterogeneous hydrogenation of sugars with H2, usually with none to low stereoselectivities. Now, we present a homogeneous system based on commerc...
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| Main Authors: | , , , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2021
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| In: |
Angewandte Chemie. International edition
Year: 2020, Volume: 60, Issue: 2, Pages: 721-725 |
| ISSN: | 1521-3773 |
| DOI: | 10.1002/anie.202009790 |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1002/anie.202009790 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202009790 
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| Author Notes: | Daniel J. Tindall, Steffen Mader, Alois Kindler, Frank Rominger, A. Stephen K. Hashmi, and Thomas Schaub |
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| 520 | |a Sugar alcohols are of great importance for the food industry and are promising building blocks for bio-based polymers. Industrially, they are produced by heterogeneous hydrogenation of sugars with H2, usually with none to low stereoselectivities. Now, we present a homogeneous system based on commercially available components, which not only increases the overall yield, but also allows a wide range of unprotected ketoses to be diastereoselectively hydrogenated. Furthermore, the system is reliable on a multi-gram scale allowing sugar alcohols to be isolated in large quantities at high atom economy. | ||
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