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Synthesis and exfoliation of a new layered mesoporous Zr-MOF comprising hexa- and dodecanuclear clusters as well as a small organic linker molecule

A new layered mesoporous Zr-MOF of composition [Zr30O20(OH)26(OAc)18L18] was synthesized by employing 5-acetamidoisophthalic acid (H2L) using acetic acid as the solvent. The new MOF, denoted as CAU-45, exhibits a honeycomb structure of stacked layers which comprise both hexa- and dodecanucelar zirco...

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Bibliographic Details
Main Authors: Leubner, Sebastian (Author) , Synnatschke, Kevin (Author) , Backes, Claudia (Author)
Format: Article (Journal)
Language:English
Published: August 21, 2020
In: Journal of the American Chemical Society
Year: 2020, Volume: 142, Issue: 37, Pages: 15995-16000
ISSN:1520-5126
DOI:10.1021/jacs.0c06978
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jacs.0c06978
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Author Notes:Sebastian Leubner, Viktor E. G. Bengtsson, Kevin Synnatschke, Jonas Gosch, Alexander Koch, Helge Reinsch, Hongyi Xu, Claudia Backes, Xiaodong Zou, and Norbert Stock

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