Synthesis and exfoliation of a new layered mesoporous Zr-MOF comprising hexa- and dodecanuclear clusters as well as a small organic linker molecule
A new layered mesoporous Zr-MOF of composition [Zr30O20(OH)26(OAc)18L18] was synthesized by employing 5-acetamidoisophthalic acid (H2L) using acetic acid as the solvent. The new MOF, denoted as CAU-45, exhibits a honeycomb structure of stacked layers which comprise both hexa- and dodecanucelar zirco...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
August 21, 2020
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| In: |
Journal of the American Chemical Society
Year: 2020, Volume: 142, Issue: 37, Pages: 15995-16000 |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/jacs.0c06978 |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/jacs.0c06978
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| Author Notes: | Sebastian Leubner, Viktor E. G. Bengtsson, Kevin Synnatschke, Jonas Gosch, Alexander Koch, Helge Reinsch, Hongyi Xu, Claudia Backes, Xiaodong Zou, and Norbert Stock |
| Summary: | A new layered mesoporous Zr-MOF of composition [Zr30O20(OH)26(OAc)18L18] was synthesized by employing 5-acetamidoisophthalic acid (H2L) using acetic acid as the solvent. The new MOF, denoted as CAU-45, exhibits a honeycomb structure of stacked layers which comprise both hexa- and dodecanucelar zirconium clusters. Its structure was solved from submicrometer-sized crystals by continuous rotation electron diffraction (cRED). Liquid phase exfoliation and size selection were successfully performed on the material. |
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| Item Description: | Gesehen am 03.11.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1520-5126 |
| DOI: | 10.1021/jacs.0c06978 |