Reaction of N,N′-bridged 1,10-diazacyclooctadeca-5,14-diynes with [CpCo(cod)]: a new type of superphane
The reaction of N,N′-bridged 1,10-diazacyclooctadeca-5,14-diynes 1a-d with [CpCo(cod)] (2) leads to both intra- (3) and inter-molecular (4) CpCo-cyclobutadiene complexes. The yield of intramolecular complex decreases and the yield of intermolecular complex increases with growing length of the alkane...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
15 Feb 2000
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| In: |
Dalton transactions
Year: 2000, Heft: 5, Pages: 685-687 |
| ISSN: | 1477-9234 |
| DOI: | 10.1039/A909482B |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1039/A909482B Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2000/dt/a909482b 
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| Verfasserangaben: | Rolf Gleiter, Thomas von Hirschheydt, Volker Wolfart and Frank Rominger |
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| 520 | |a The reaction of N,N′-bridged 1,10-diazacyclooctadeca-5,14-diynes 1a-d with [CpCo(cod)] (2) leads to both intra- (3) and inter-molecular (4) CpCo-cyclobutadiene complexes. The yield of intramolecular complex decreases and the yield of intermolecular complex increases with growing length of the alkane bridge. X-Ray investigations on single crystals of 3a, 3d and 4d reveal that the repulsions between the Cp ring and two CH2-groups in β-position to the cyclobutadiene ring increase from 3a to 3d. Such steric repulsions are not found in 4d. | ||
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