Syntheses and solid state structures of cyclic diynes with two chalcogen centres: a competition between weak interactions
In this paper we report the synthesis of cyclic diynes of the general formula mX2n. The letters m and n indicate the lengths of chains between two CC-X units where X indicates S, Se, or Te. The lengths of the bridges vary between m = 4-8 and n = 2-6. Structural investigations by means of X-ray diffr...
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| Main Authors: | , , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
26th June 2003
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| In: |
Organic & biomolecular chemistry
Year: 2003, Volume: 1, Issue: 15, Pages: 2788-2794 |
| ISSN: | 1477-0539 |
| DOI: | 10.1039/B303653G |
| Online Access: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1039/B303653G Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2003/ob/b303653g 
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| Author Notes: | J. Hilko Schulte, Daniel B. Werz, Frank Rominger and Rolf Gleiter |
| Summary: | In this paper we report the synthesis of cyclic diynes of the general formula mX2n. The letters m and n indicate the lengths of chains between two CC-X units where X indicates S, Se, or Te. The lengths of the bridges vary between m = 4-8 and n = 2-6. Structural investigations by means of X-ray diffraction reveal for most systems a chair-like conformation in the solid state. For 5S22, 5S23, 7S25, 5Se22 and 5Te23 tubular structures were encountered. These structures can be traced back to weak X⋯X or weak C-H⋯π interactions. |
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| Item Description: | Gesehen am 06.11.2020 |
| Physical Description: | Online Resource |
| ISSN: | 1477-0539 |
| DOI: | 10.1039/B303653G |