Dual gold catalysis: Synthesis of polycyclic compounds via C-H insertion of gold vinylidenes
New and interesting polycyclic compounds have been synthesized from non-conjugated diyne systems by dual gold catalysis. A quaternary carbon center in the backbone and the accompanying Thorpe-Ingold effect enabled the unprecedented insertion of sp3 and sp2 CH bonds that for the first time were inco...
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| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
08 October 2014
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| In: |
Chemistry - a European journal
Year: 2014, Jahrgang: 20, Heft: 49, Pages: 16331-16336 |
| ISSN: | 1521-3765 |
| DOI: | https://doi.org/10.1002/chem.201404987 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/chem.201404987 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201404987 
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| Verfasserangaben: | Marcel Wieteck, Yusuke Tokimizu, Matthias Rudolph, Frank Rominger, Hiroaki Ohno, Nobutaka Fujii, and A. Stephen K. Hashmi |
MARC
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| 520 | |a New and interesting polycyclic compounds have been synthesized from non-conjugated diyne systems by dual gold catalysis. A quaternary carbon center in the backbone and the accompanying Thorpe-Ingold effect enabled the unprecedented insertion of sp3 and sp2 CH bonds that for the first time were incorporated within the backbone of the diyne system and allowed the construction of complex polycyclic carbon scaffolds inaccessible by previous approaches in which the CH bonds for the insertion were situated at the other end of the alkyne. | ||
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