Dual gold catalysis: Synthesis of polycyclic compounds via C-H insertion of gold vinylidenes

New and interesting polycyclic compounds have been synthesized from non-conjugated diyne systems by dual gold catalysis. A quaternary carbon center in the backbone and the accompanying Thorpe-Ingold effect enabled the unprecedented insertion of sp3 and sp2 CH bonds that for the first time were inco...

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Bibliographic Details

Main Authors:	Wieteck, Marcel (Author) , Rudolph, Matthias (Author) , Rominger, Frank (Author) , Hashmi, A. Stephen K. (Author)
Format:	Article (Journal)
Language:	English
Published:	08 October 2014
In:	Chemistry - a European journal Year: 2014, Volume: 20, Issue: 49, Pages: 16331-16336
ISSN:	1521-3765
DOI:	https://doi.org/10.1002/chem.201404987
Online Access:	Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/chem.201404987 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201404987
Author Notes:	Marcel Wieteck, Yusuke Tokimizu, Matthias Rudolph, Frank Rominger, Hiroaki Ohno, Nobutaka Fujii, and A. Stephen K. Hashmi