Synthesis and properties of donor-acceptor-substituted metal-capped fourfold-bridged cyclobutadienophanes
The synthesis of the superphanes 4−8 could be achieved from {(1,2,11,12-η4)-tricyclo[10.8.0.02,11]eicosa-1,11-diene-6,17-diyne}(η5-cyclopentadienyl)cobalt (15) and its methoxycarbonyl congener 14 by heating with R−CpCo(CO)2 (R = H, CH3, (CH3)5). X-ray investigations on the superphanes 3, 6, and 8 re...
Gespeichert in:
| Hauptverfasser: | , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2000
|
| In: |
Organometallics
Year: 1999, Jahrgang: 19, Heft: 2, Pages: 147-151 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om9907270 |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/om9907270 Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/abs/10.1021/om9907270 
|
| Verfasserangaben: | Rolf Gleiter, Rolf Roers, Jörg Classen, Albrecht Jacobi, Gottfried Huttner, and Thomas Oeser |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 173830776X | ||
| 003 | DE-627 | ||
| 005 | 20230428161339.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 201110r20001999xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1021/om9907270 |2 doi | |
| 035 | |a (DE-627)173830776X | ||
| 035 | |a (DE-599)KXP173830776X | ||
| 035 | |a (OCoLC)1341376007 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 30 |2 sdnb | ||
| 100 | 1 | |a Gleiter, Rolf |d 1936- |e VerfasserIn |0 (DE-588)1035293870 |0 (DE-627)747237077 |0 (DE-576)382908473 |4 aut | |
| 245 | 1 | 0 | |a Synthesis and properties of donor-acceptor-substituted metal-capped fourfold-bridged cyclobutadienophanes |c Rolf Gleiter, Rolf Roers, Jörg Classen, Albrecht Jacobi, Gottfried Huttner, and Thomas Oeser |
| 264 | 1 | |c 2000 | |
| 300 | |a 5 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Publication on Web 12/18/1999 | ||
| 500 | |a Gesehen am 10.11.2020 | ||
| 520 | |a The synthesis of the superphanes 4−8 could be achieved from {(1,2,11,12-η4)-tricyclo[10.8.0.02,11]eicosa-1,11-diene-6,17-diyne}(η5-cyclopentadienyl)cobalt (15) and its methoxycarbonyl congener 14 by heating with R−CpCo(CO)2 (R = H, CH3, (CH3)5). X-ray investigations on the superphanes 3, 6, and 8 reveal distances between the two cyclobutadiene units between 2.922 Å (3) and 2.941 Å (6). Investigations by means of cyclic voltammetry show a decrease of the first oxidation potentials with increasing number of CH3 substituents at the cyclopentadienyl ligands. The comparison between the first oxidation potentials of 2−6, 4−7, and 5−8 gives evidence for a partial charge delocalization over both CpCoCb fragments of the superphanes. | ||
| 534 | |c 1999 | ||
| 700 | 1 | |a Roers, Rolf |e VerfasserIn |0 (DE-588)1220510254 |0 (DE-627)1737432595 |4 aut | |
| 700 | 1 | |a Claßen, Jörg |e VerfasserIn |0 (DE-588)122039176X |0 (DE-627)1736895966 |4 aut | |
| 700 | 1 | |a Jacobi, Albrecht |e VerfasserIn |0 (DE-588)1221157191 |0 (DE-627)1738311945 |4 aut | |
| 700 | 1 | |a Huttner, Gottfried |d 1937-2021 |e VerfasserIn |0 (DE-588)173131352 |0 (DE-627)698053826 |0 (DE-576)133982734 |4 aut | |
| 700 | 1 | |a Oeser, Thomas |e VerfasserIn |0 (DE-588)1025249038 |0 (DE-627)721919715 |0 (DE-576)170725553 |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Organometallics |d Washington, DC : ACS Publ., 1982 |g 19(2000), 2, Seite 147-151 |h Online-Ressource |w (DE-627)320453111 |w (DE-600)2006302-7 |w (DE-576)09088941X |x 1520-6041 |7 nnas |a Synthesis and properties of donor-acceptor-substituted metal-capped fourfold-bridged cyclobutadienophanes |
| 773 | 1 | 8 | |g volume:19 |g year:2000 |g number:2 |g pages:147-151 |g extent:5 |a Synthesis and properties of donor-acceptor-substituted metal-capped fourfold-bridged cyclobutadienophanes |
| 856 | 4 | 0 | |u https://doi.org/10.1021/om9907270 |x Resolving-System |x Verlag |z lizenzpflichtig |3 Volltext |
| 856 | 4 | 0 | |u https://pubs.acs.org/doi/abs/10.1021/om9907270 |x Verlag |z lizenzpflichtig |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20201110 | ||
| 993 | |a Article | ||
| 994 | |a 2000 | ||
| 998 | |g 1025249038 |a Oeser, Thomas |m 1025249038:Oeser, Thomas |d 120000 |d 120100 |e 120000PO1025249038 |e 120100PO1025249038 |k 0/120000/ |k 1/120000/120100/ |p 6 |y j | ||
| 998 | |g 173131352 |a Huttner, Gottfried |m 173131352:Huttner, Gottfried |d 120000 |d 120200 |e 120000PH173131352 |e 120200PH173131352 |k 0/120000/ |k 1/120000/120200/ |p 5 | ||
| 998 | |g 1221157191 |a Jacobi, Albrecht |m 1221157191:Jacobi, Albrecht |d 120000 |d 120200 |e 120000PJ1221157191 |e 120200PJ1221157191 |k 0/120000/ |k 1/120000/120200/ |p 4 | ||
| 998 | |g 122039176X |a Claßen, Jörg |m 122039176X:Claßen, Jörg |d 120000 |d 120100 |e 120000PC122039176X |e 120100PC122039176X |k 0/120000/ |k 1/120000/120100/ |p 3 | ||
| 998 | |g 1220510254 |a Roers, Rolf |m 1220510254:Roers, Rolf |d 120000 |d 120100 |e 120000PR1220510254 |e 120100PR1220510254 |k 0/120000/ |k 1/120000/120100/ |p 2 | ||
| 998 | |g 1035293870 |a Gleiter, Rolf |m 1035293870:Gleiter, Rolf |d 120000 |d 120100 |e 120000PG1035293870 |e 120100PG1035293870 |k 0/120000/ |k 1/120000/120100/ |p 1 |x j | ||
| 999 | |a KXP-PPN173830776X |e 3796336361 | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"name":{"displayForm":["Rolf Gleiter, Rolf Roers, Jörg Classen, Albrecht Jacobi, Gottfried Huttner, and Thomas Oeser"]},"id":{"eki":["173830776X"],"doi":["10.1021/om9907270"]},"origin":[{"dateIssuedDisp":"2000","dateIssuedKey":"2000"}],"relHost":[{"pubHistory":["1.1982 -"],"part":{"extent":"5","volume":"19","text":"19(2000), 2, Seite 147-151","pages":"147-151","issue":"2","year":"2000"},"disp":"Synthesis and properties of donor-acceptor-substituted metal-capped fourfold-bridged cyclobutadienophanesOrganometallics","type":{"media":"Online-Ressource","bibl":"periodical"},"note":["Gesehen am 22.03.23"],"language":["eng"],"recId":"320453111","title":[{"subtitle":"web edition","title":"Organometallics","title_sort":"Organometallics"}],"physDesc":[{"extent":"Online-Ressource"}],"origin":[{"publisher":"ACS Publ.","dateIssuedKey":"1982","dateIssuedDisp":"1982-","publisherPlace":"Washington, DC"}],"id":{"eki":["320453111"],"zdb":["2006302-7"],"issn":["1520-6041"]},"name":{"displayForm":["American Chemical Society"]}}],"physDesc":[{"extent":"5 S."}],"person":[{"roleDisplay":"VerfasserIn","display":"Gleiter, Rolf","role":"aut","family":"Gleiter","given":"Rolf"},{"given":"Rolf","family":"Roers","role":"aut","display":"Roers, Rolf","roleDisplay":"VerfasserIn"},{"display":"Claßen, Jörg","roleDisplay":"VerfasserIn","role":"aut","family":"Claßen","given":"Jörg"},{"role":"aut","roleDisplay":"VerfasserIn","display":"Jacobi, Albrecht","given":"Albrecht","family":"Jacobi"},{"role":"aut","display":"Huttner, Gottfried","roleDisplay":"VerfasserIn","given":"Gottfried","family":"Huttner"},{"family":"Oeser","given":"Thomas","display":"Oeser, Thomas","roleDisplay":"VerfasserIn","role":"aut"}],"title":[{"title":"Synthesis and properties of donor-acceptor-substituted metal-capped fourfold-bridged cyclobutadienophanes","title_sort":"Synthesis and properties of donor-acceptor-substituted metal-capped fourfold-bridged cyclobutadienophanes"}],"recId":"173830776X","language":["eng"],"note":["Publication on Web 12/18/1999","Gesehen am 10.11.2020"],"type":{"media":"Online-Ressource","bibl":"article-journal"}} | ||
| SRT | |a GLEITERROLSYNTHESISA2000 | ||