Isolation of bis(η2-nitrato)(η4-cyclobutadiene)cobalt(II) complexes from the oxidation of sterically hindered CpCo-stabilized cyclobutadiene complexes
The oxidation of sterically hindered, CpCo-protected cyclobutadienes with ceric ammonium nitrate (CAN) yielded the paramagnetic Co(NO3)2-protected cyclobutadiene products. These half-sandwich complexes represent possible intermediates within the mechanism of the CAN decomplexation of CpCo−cyclobutad...
Gespeichert in:
| Hauptverfasser: | , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
04/15/2004
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| In: |
Organometallics
Year: 2004, Jahrgang: 23, Heft: 10, Pages: 2225-2227 |
| ISSN: | 1520-6041 |
| DOI: | 10.1021/om049907m |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/om049907m Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/abs/10.1021/om049907m 
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| Verfasserangaben: | Carsten Schaefer, Rolf Gleiter, and Frank Rominger |
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| 246 | 3 | 3 | |a Isolation of bis(eta2-nitrato)(eta4-cyclobutadiene)cobalt(II) complexes from the oxidation of sterically hindered CpCo-stabilized cyclobutadiene complexes |
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| 520 | |a The oxidation of sterically hindered, CpCo-protected cyclobutadienes with ceric ammonium nitrate (CAN) yielded the paramagnetic Co(NO3)2-protected cyclobutadiene products. These half-sandwich complexes represent possible intermediates within the mechanism of the CAN decomplexation of CpCo−cyclobutadiene complexes. | ||
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