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CpCo-stabilized cyclopentadienones from cyclobutadiene complexes: experimental and theoretical investigations

The reaction of 1,4,8,11-tetrathiacyclotetradeca-2,9-diyne (7) with C5H4(CO2Me)Co(CO)2 (8) and C5H4(SiMe3)Co(CO)2 (10) led to the tricyclic cyclopentadienone complexes 9 and 11. In both species the CO was inserted into a former triple bond. This observation led to the preparation of the tetrathiaalk...

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Bibliographische Detailangaben
Hauptverfasser: Schaefer, Carsten (VerfasserIn) , Werz, Daniel B. (VerfasserIn) , Stäb, Tobias (VerfasserIn) , Gleiter, Rolf (VerfasserIn) , Rominger, Frank (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 03/23/2005
In: Organometallics
Year: 2005, Jahrgang: 24, Heft: 9, Pages: 2106-2113
ISSN:1520-6041
DOI:10.1021/om050048r
Online-Zugang:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1021/om050048r
Verlag, lizenzpflichtig, Volltext: https://pubs.acs.org/doi/10.1021/om050048r
Volltext
Verfasserangaben:Carsten Schaefer, Daniel B. Werz, Tobias H. Staeb, Rolf Gleiter, and Frank Rominger

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