Synthesis of new conjugated diynes containing carbamate groups, and study of their properties
Carbamates of monoacetylene and diacetylene series were synthesized and characterized. A catalytic system CuI-pyrrolidine was applied for the first time to a synthesis of symmetrical diacetylenes by oxidative dimerization of terminal acetylenes. The comparative activity of diynes obtained was studie...
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| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
June 2002
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| In: |
Russian journal of organic chemistry
Year: 2002, Jahrgang: 38, Heft: 6, Pages: 775-787 |
| ISSN: | 1608-3393 |
| DOI: | 10.1023/A:1020326818084 |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1023/A:1020326818084 Verlag, lizenzpflichtig, Volltext: https://link.springer.com/article/10.1023/A:1020326818084 
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| Verfasserangaben: | S. Yu. Vyazmin, S.E. Berezina, L.A. Remizova, I.N. Domnin, R. Gleiter |
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| 520 | |a Carbamates of monoacetylene and diacetylene series were synthesized and characterized. A catalytic system CuI-pyrrolidine was applied for the first time to a synthesis of symmetrical diacetylenes by oxidative dimerization of terminal acetylenes. The comparative activity of diynes obtained was studied in the photoinitiated solid-phase topochemical polymerization. Diyne carbamates undergoing thermal polymerization were obtained for the first time. | ||
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