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Synthesis of new conjugated diynes containing carbamate groups, and study of their properties

Carbamates of monoacetylene and diacetylene series were synthesized and characterized. A catalytic system CuI-pyrrolidine was applied for the first time to a synthesis of symmetrical diacetylenes by oxidative dimerization of terminal acetylenes. The comparative activity of diynes obtained was studie...

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Bibliographische Detailangaben
Hauptverfasser: Vyazmin, Sergey (VerfasserIn) , Berezina, S. E. (VerfasserIn) , Remizova, L. A. (VerfasserIn) , Domnin, I. N. (VerfasserIn) , Gleiter, Rolf (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: June 2002
In: Russian journal of organic chemistry
Year: 2002, Jahrgang: 38, Heft: 6, Pages: 775-787
ISSN:1608-3393
DOI:10.1023/A:1020326818084
Online-Zugang:Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1023/A:1020326818084
Verlag, lizenzpflichtig, Volltext: https://link.springer.com/article/10.1023/A:1020326818084
Volltext
Verfasserangaben:S. Yu. Vyazmin, S.E. Berezina, L.A. Remizova, I.N. Domnin, R. Gleiter
Beschreibung
Zusammenfassung:Carbamates of monoacetylene and diacetylene series were synthesized and characterized. A catalytic system CuI-pyrrolidine was applied for the first time to a synthesis of symmetrical diacetylenes by oxidative dimerization of terminal acetylenes. The comparative activity of diynes obtained was studied in the photoinitiated solid-phase topochemical polymerization. Diyne carbamates undergoing thermal polymerization were obtained for the first time.
Beschreibung:Gesehen am 11.11.2020
Beschreibung:Online Resource
ISSN:1608-3393
DOI:10.1023/A:1020326818084

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