Thiabowls: synthesis, molecular structure and the solid state architecture of tetrathia-[4]-peristylane
Synthesis of tetrathia-[4]-peristylane, the first thiabowl, from the dimer of cyclooctatetraene has been accomplished. The X-ray crystal structure of the tetrathiabowl indicates significant departure from the expected C4v symmetry and in the solid state it exhibits a multi-columnar arrangement and a...
Gespeichert in:
| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
26 November 2003
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| In: |
Tetrahedron letters
Year: 2003, Jahrgang: 44, Heft: 52, Pages: 9313-9316 |
| ISSN: | 1873-3581 |
| DOI: | 10.1016/j.tetlet.2003.10.038 |
| Online-Zugang: | Resolving-System, lizenzpflichtig, Volltext: https://doi.org/10.1016/j.tetlet.2003.10.038 Verlag, lizenzpflichtig, Volltext: https://www.sciencedirect.com/science/article/pii/S0040403903024481 
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| Verfasserangaben: | Goverdhan Mehta, Vanessa Gagliardini, Carsten Schaefer and Rolf Gleiter |
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| 520 | |a Synthesis of tetrathia-[4]-peristylane, the first thiabowl, from the dimer of cyclooctatetraene has been accomplished. The X-ray crystal structure of the tetrathiabowl indicates significant departure from the expected C4v symmetry and in the solid state it exhibits a multi-columnar arrangement and a novel ‘self-inclusion’ phenomenon, directed by a network of S⋯S and CH⋯S interactions. | ||
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