Isolation and structure elucidation of the major individual polyphenols in carob fibre
Although it is already known that carob fibre contains several classes of polyphenolic substances, a comprehensive analysis of these has not been conducted to date. Therefore, the major polyphenolic compounds were extracted with organic solvents, and, following fractionation by normal-phase column c...
Gespeichert in:
| Hauptverfasser: | , , , , , , |
|---|---|
| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
29 August 2003
|
| In: |
Food and chemical toxicology
Year: 2003, Jahrgang: 41, Heft: 12, Pages: 1727-1738 |
| ISSN: | 1873-6351 |
| DOI: | 10.1016/S0278-6915(03)00200-X |
| Online-Zugang: | Verlag, Volltext: https://doi.org/10.1016/S0278-6915(03)00200-X Verlag, Volltext: http://www.sciencedirect.com/science/article/pii/S027869150300200X 
|
| Verfasserangaben: | R.W. Owen, R. Haubner, W.E. Hull, G. Erben, B. Spiegelhalder, H. Bartsch, B. Haber |
MARC
| LEADER | 00000caa a2200000 c 4500 | ||
|---|---|---|---|
| 001 | 1740425901 | ||
| 003 | DE-627 | ||
| 005 | 20230428084937.0 | ||
| 007 | cr uuu---uuuuu | ||
| 008 | 201123s2003 xx |||||o 00| ||eng c | ||
| 024 | 7 | |a 10.1016/S0278-6915(03)00200-X |2 doi | |
| 035 | |a (DE-627)1740425901 | ||
| 035 | |a (DE-599)KXP1740425901 | ||
| 035 | |a (OCoLC)1341377834 | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rda | ||
| 041 | |a eng | ||
| 084 | |a 33 |2 sdnb | ||
| 100 | 1 | |a Owen, Robert |e VerfasserIn |0 (DE-588)1082251887 |0 (DE-627)847252019 |0 (DE-576)455284539 |4 aut | |
| 245 | 1 | 0 | |a Isolation and structure elucidation of the major individual polyphenols in carob fibre |c R.W. Owen, R. Haubner, W.E. Hull, G. Erben, B. Spiegelhalder, H. Bartsch, B. Haber |
| 264 | 1 | |c 29 August 2003 | |
| 300 | |a 12 | ||
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a Computermedien |b c |2 rdamedia | ||
| 338 | |a Online-Ressource |b cr |2 rdacarrier | ||
| 500 | |a Gesehen am 23.11.2020 | ||
| 520 | |a Although it is already known that carob fibre contains several classes of polyphenolic substances, a comprehensive analysis of these has not been conducted to date. Therefore, the major polyphenolic compounds were extracted with organic solvents, and, following fractionation by normal-phase column chromatography on silicic acid, their structures were elucidated by liquid-chromatography electrospray-ionisation mass spectrometry (LC-ESI), nano-electrospray-ionisation mass spectrometry (ESI-MS), and gas-chromatography mass spectrometry (GC-MS). In addition, complete 1H and 13C NMR assignments were obtained for the isolated gallotannins 1,6-di-, 1,2,6-tri- and 1,2,3,6-tetra-O-galloyl-β-d-glucose. Carob fibre was found to contain a rich variety of phenolic antioxidants. A total of 24 polyphenol compounds were identified with a yield of 3.94 g/kg (dry weight). The profile was dominated by gallic acid in various forms: free gallic acid (42% of polyphenols by weight), gallotannins (29%), and methyl gallate (1%), while simple phenols, mainly cinnamic acid, made up about 2% of the total. Flavonoids represented 26% of the polyphenols, and the major components were identified as the glycosides myricetin- and quercetin-3-O-α-l-rhamnoside (ca. 9% and 10%, respectively). These data indicate that carob fibre is rich in both amount and variety of phenolic antioxidant substances, and its inclusion in the diet may have chemopreventive properties. | ||
| 650 | 4 | |a Antioxidants | |
| 650 | 4 | |a Carob fibre | |
| 650 | 4 | |a Flavonoids | |
| 650 | 4 | |a HPLC | |
| 650 | 4 | |a Mass spectrometry | |
| 650 | 4 | |a Mediterranean diet | |
| 650 | 4 | |a NMR | |
| 650 | 4 | |a Polyphenols | |
| 700 | 1 | |a Haubner, R. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Hull, William Edmund |e VerfasserIn |0 (DE-588)1180547306 |0 (DE-627)1067775978 |0 (DE-576)520275551 |4 aut | |
| 700 | 1 | |a Erben, G. |e VerfasserIn |4 aut | |
| 700 | 1 | |a Spiegelhalder, Bertold |e VerfasserIn |0 (DE-588)1180547519 |0 (DE-627)1067776273 |0 (DE-576)520276167 |4 aut | |
| 700 | 1 | |a Bartsch, Helmut |d 1940- |e VerfasserIn |0 (DE-588)1021102032 |0 (DE-627)691457018 |0 (DE-576)362545545 |4 aut | |
| 700 | 1 | |a Haber, B. |e VerfasserIn |4 aut | |
| 773 | 0 | 8 | |i Enthalten in |t Food and chemical toxicology |d New York, NY [u.a.] : Elsevier, 1982 |g 41(2003), 12, Seite 1727-1738 |h Online-Ressource |w (DE-627)300898487 |w (DE-600)1483645-2 |w (DE-576)259270849 |x 1873-6351 |7 nnas |a Isolation and structure elucidation of the major individual polyphenols in carob fibre |
| 773 | 1 | 8 | |g volume:41 |g year:2003 |g number:12 |g pages:1727-1738 |g extent:12 |a Isolation and structure elucidation of the major individual polyphenols in carob fibre |
| 856 | 4 | 0 | |u https://doi.org/10.1016/S0278-6915(03)00200-X |x Verlag |x Resolving-System |3 Volltext |
| 856 | 4 | 0 | |u http://www.sciencedirect.com/science/article/pii/S027869150300200X |x Verlag |3 Volltext |
| 951 | |a AR | ||
| 992 | |a 20201123 | ||
| 993 | |a Article | ||
| 994 | |a 2003 | ||
| 998 | |g 1021102032 |a Bartsch, Helmut |m 1021102032:Bartsch, Helmut |d 50000 |e 50000PB1021102032 |k 0/50000/ |p 6 | ||
| 998 | |g 1180547519 |a Spiegelhalder, Bertold |m 1180547519:Spiegelhalder, Bertold |d 50000 |e 50000PS1180547519 |k 0/50000/ |p 5 | ||
| 998 | |g 1180547306 |a Hull, William Edmund |m 1180547306:Hull, William Edmund |d 50000 |e 50000PH1180547306 |k 0/50000/ |p 3 | ||
| 998 | |g 1082251887 |a Owen, Robert |m 1082251887:Owen, Robert |d 50000 |e 50000PO1082251887 |k 0/50000/ |p 1 |x j | ||
| 999 | |a KXP-PPN1740425901 |e 381057127X | ||
| BIB | |a Y | ||
| SER | |a journal | ||
| JSO | |a {"title":[{"title_sort":"Isolation and structure elucidation of the major individual polyphenols in carob fibre","title":"Isolation and structure elucidation of the major individual polyphenols in carob fibre"}],"person":[{"given":"Robert","family":"Owen","role":"aut","roleDisplay":"VerfasserIn","display":"Owen, Robert"},{"role":"aut","display":"Haubner, R.","roleDisplay":"VerfasserIn","given":"R.","family":"Haubner"},{"family":"Hull","given":"William Edmund","display":"Hull, William Edmund","roleDisplay":"VerfasserIn","role":"aut"},{"family":"Erben","given":"G.","roleDisplay":"VerfasserIn","display":"Erben, G.","role":"aut"},{"roleDisplay":"VerfasserIn","display":"Spiegelhalder, Bertold","role":"aut","family":"Spiegelhalder","given":"Bertold"},{"role":"aut","roleDisplay":"VerfasserIn","display":"Bartsch, Helmut","given":"Helmut","family":"Bartsch"},{"given":"B.","family":"Haber","role":"aut","display":"Haber, B.","roleDisplay":"VerfasserIn"}],"note":["Gesehen am 23.11.2020"],"type":{"bibl":"article-journal","media":"Online-Ressource"},"recId":"1740425901","language":["eng"],"origin":[{"dateIssuedDisp":"29 August 2003","dateIssuedKey":"2003"}],"id":{"doi":["10.1016/S0278-6915(03)00200-X"],"eki":["1740425901"]},"name":{"displayForm":["R.W. Owen, R. Haubner, W.E. Hull, G. Erben, B. Spiegelhalder, H. Bartsch, B. Haber"]},"physDesc":[{"extent":"12 S."}],"relHost":[{"type":{"bibl":"periodical","media":"Online-Ressource"},"disp":"Isolation and structure elucidation of the major individual polyphenols in carob fibreFood and chemical toxicology","note":["Gesehen am 29.03.11"],"language":["eng"],"recId":"300898487","pubHistory":["20.1982 - 50.2012; Vol. 51.2013 -"],"part":{"pages":"1727-1738","issue":"12","year":"2003","extent":"12","volume":"41","text":"41(2003), 12, Seite 1727-1738"},"title":[{"title_sort":"Food and chemical toxicology","title":"Food and chemical toxicology"}],"physDesc":[{"extent":"Online-Ressource"}],"origin":[{"dateIssuedKey":"1982","publisher":"Elsevier","dateIssuedDisp":"1982-","publisherPlace":"New York, NY [u.a.]"}],"id":{"zdb":["1483645-2"],"eki":["300898487"],"issn":["1873-6351"]}}]} | ||
| SRT | |a OWENROBERTISOLATIONA2920 | ||