Buchumschlag

The pH dependence of Am(III) complexation with acetate: an EXAFS study

The complexation of acetate with Am(III) is studied as a function of the pH (1-6) by extended X-ray absorption fine-structure (EXAFS) spectroscopy. The molecular structure of the Am(III)-acetate complexes (coordination numbers, oxygen and carbon distances) is determined from the raw - k - 3 - -weigh...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Fröhlich, Daniel R. (VerfasserIn) , Skerencak-Frech, Andrej (VerfasserIn) , Bauer, Nicole (VerfasserIn) , Roßberg, André (VerfasserIn) , Panak, Petra (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: January 2015
In: Journal of synchrotron radiation
Year: 2015, Jahrgang: 22, Pages: 99-104
ISSN:1600-5775
DOI:10.1107/S1600577514022498
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1107/S1600577514022498
Volltext
Verfasserangaben:Daniel R. Fröhlich, Andrej Skerencak-Frech, Nicole Bauer, André Rossberg, and Petra J. Panak

MARC

LEADER 00000caa a2200000 c 4500
001 174089376X
003 DE-627
005 20230428085023.0
007 cr uuu---uuuuu
008 201124s2015 xx |||||o 00| ||eng c
024 7 |a 10.1107/S1600577514022498  |2 doi 
035 |a (DE-627)174089376X 
035 |a (DE-599)KXP174089376X 
035 |a (OCoLC)1341378060 
040 |a DE-627  |b ger  |c DE-627  |e rda 
041 |a eng 
084 |a 30  |2 sdnb 
100 1 |a Fröhlich, Daniel R.  |d 1983-  |e VerfasserIn  |0 (DE-588)1018306005  |0 (DE-627)690574258  |0 (DE-576)355608103  |4 aut 
245 1 4 |a The pH dependence of Am(III) complexation with acetate  |b an EXAFS study  |c Daniel R. Fröhlich, Andrej Skerencak-Frech, Nicole Bauer, André Rossberg, and Petra J. Panak 
264 1 |c January 2015 
300 |a 6 
336 |a Text  |b txt  |2 rdacontent 
337 |a Computermedien  |b c  |2 rdamedia 
338 |a Online-Ressource  |b cr  |2 rdacarrier 
500 |a Gesehen am 24.11.2020 
520 |a The complexation of acetate with Am(III) is studied as a function of the pH (1-6) by extended X-ray absorption fine-structure (EXAFS) spectroscopy. The molecular structure of the Am(III)-acetate complexes (coordination numbers, oxygen and carbon distances) is determined from the raw - k - 3 - -weighted Am - L - III - -edge EXAFS spectra. The results show a continuous shift of Am(III) speciation with increasing pH value towards the complexed species. Furthermore, it is verified that acetate coordinates in a bidentate coordination mode to Am(III) (Am—C distance: 2.82 ± 0.03 Å). The EXAFS data are analyzed by iterative transformation factor analysis to further verify the chemical speciation, which is calculated on the basis of thermodynamic constants, and the used structural model. The experimental results are in very good agreement with the thermodynamic modelling. 
700 1 |a Skerencak-Frech, Andrej  |e VerfasserIn  |0 (DE-588)141626550  |0 (DE-627)630395519  |0 (DE-576)325028133  |4 aut 
700 1 |a Bauer, Nicole  |e VerfasserIn  |0 (DE-588)1071670638  |0 (DE-627)826239234  |0 (DE-576)433236647  |4 aut 
700 1 |a Roßberg, André  |d 1971-  |e VerfasserIn  |0 (DE-588)124292119  |0 (DE-627)706598407  |0 (DE-576)294105336  |4 aut 
700 1 |a Panak, Petra  |e VerfasserIn  |0 (DE-588)1084656000  |0 (DE-627)848640217  |0 (DE-576)456626727  |4 aut 
773 0 8 |i Enthalten in  |t Journal of synchrotron radiation  |d Chester : IUCr, 1994  |g 22(2015), Seite 99-104  |h Online-Ressource  |w (DE-627)317885510  |w (DE-600)2021413-3  |w (DE-576)095660232  |x 1600-5775  |7 nnas  |a The pH dependence of Am(III) complexation with acetate an EXAFS study 
773 1 8 |g volume:22  |g year:2015  |g pages:99-104  |g extent:6  |a The pH dependence of Am(III) complexation with acetate an EXAFS study 
856 4 0 |u https://doi.org/10.1107/S1600577514022498  |x Verlag  |x Resolving-System  |z lizenzpflichtig  |3 Volltext 
951 |a AR 
992 |a 20201124 
993 |a Article 
994 |a 2015 
998 |g 1084656000  |a Panak, Petra  |m 1084656000:Panak, Petra  |d 120000  |d 120300  |e 120000PP1084656000  |e 120300PP1084656000  |k 0/120000/  |k 1/120000/120300/  |p 5  |y j 
998 |g 1071670638  |a Bauer, Nicole  |m 1071670638:Bauer, Nicole  |d 120000  |e 120000PB1071670638  |k 0/120000/  |p 3 
998 |g 1018306005  |a Fröhlich, Daniel R.  |m 1018306005:Fröhlich, Daniel R.  |d 120000  |d 120300  |e 120000PF1018306005  |e 120300PF1018306005  |k 0/120000/  |k 1/120000/120300/  |p 1  |x j 
999 |a KXP-PPN174089376X  |e 3811798057 
BIB |a Y 
SER |a journal 
JSO |a {"note":["Gesehen am 24.11.2020"],"person":[{"role":"aut","family":"Fröhlich","roleDisplay":"VerfasserIn","display":"Fröhlich, Daniel R.","given":"Daniel R."},{"display":"Skerencak-Frech, Andrej","given":"Andrej","role":"aut","family":"Skerencak-Frech","roleDisplay":"VerfasserIn"},{"display":"Bauer, Nicole","given":"Nicole","role":"aut","family":"Bauer","roleDisplay":"VerfasserIn"},{"given":"André","display":"Roßberg, André","family":"Roßberg","roleDisplay":"VerfasserIn","role":"aut"},{"given":"Petra","display":"Panak, Petra","roleDisplay":"VerfasserIn","family":"Panak","role":"aut"}],"type":{"media":"Online-Ressource","bibl":"article-journal"},"origin":[{"dateIssuedDisp":"January 2015","dateIssuedKey":"2015"}],"language":["eng"],"physDesc":[{"extent":"6 S."}],"name":{"displayForm":["Daniel R. Fröhlich, Andrej Skerencak-Frech, Nicole Bauer, André Rossberg, and Petra J. Panak"]},"title":[{"title":"The pH dependence of Am(III) complexation with acetate","subtitle":"an EXAFS study","title_sort":"pH dependence of Am(III) complexation with acetate"}],"recId":"174089376X","id":{"eki":["174089376X"],"doi":["10.1107/S1600577514022498"]},"relHost":[{"origin":[{"publisher":"IUCr ; Wiley-Blackwell","dateIssuedKey":"1994","publisherPlace":"Chester ; [Erscheinungsort nicht ermittelbar]","dateIssuedDisp":"1994-"}],"language":["eng"],"part":{"text":"22(2015), Seite 99-104","volume":"22","year":"2015","extent":"6","pages":"99-104"},"physDesc":[{"extent":"Online-Ressource"}],"titleAlt":[{"title":"Synchrotron radiation online"},{"title":"Synchrotron radiation"}],"name":{"displayForm":["International Union of Crystallography"]},"title":[{"title":"Journal of synchrotron radiation","title_sort":"Journal of synchrotron radiation"}],"recId":"317885510","disp":"The pH dependence of Am(III) complexation with acetate an EXAFS studyJournal of synchrotron radiation","corporate":[{"display":"Internationale Union für Kristallographie","roleDisplay":"Herausgebendes Organ","role":"isb"}],"id":{"zdb":["2021413-3"],"doi":["10.1107/S16005775"],"issn":["1600-5775"],"eki":["317885510"]},"note":["Gesehen am 24.03.2022"],"pubHistory":["1.1994 -"],"type":{"bibl":"periodical","media":"Online-Ressource"}}]} 
SRT |a FROEHLICHDPHDEPENDEN2015 

Ähnliche Einträge