Selective even-numbered bromination of triptycene tris(thiadiazoles)
An unusual even-numbered bromination of triptycene tristhiadiazole is described, giving selectively dibromo-, tetrabromo-, and hexabromotriptycenes with two bromines each at the same phenyl ring. The new compounds can be used as precursors for extended π-conjugated systems and polymers.
Gespeichert in:
| Hauptverfasser: | , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
October 21, 2014
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| In: |
Organic letters
Year: 2014, Jahrgang: 16, Heft: 21, Pages: 5596-5599 |
| ISSN: | 1523-7052 |
| DOI: | 10.1021/ol502639x |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/ol502639x
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| Verfasserangaben: | Bernd Kohl, Lena Charlotte Over, Thorsten Lohr, Mariya Vasylyeva, Frank Rominger, and Michael Mastalerz |
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| 520 | |a An unusual even-numbered bromination of triptycene tristhiadiazole is described, giving selectively dibromo-, tetrabromo-, and hexabromotriptycenes with two bromines each at the same phenyl ring. The new compounds can be used as precursors for extended π-conjugated systems and polymers. | ||
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