Synthesis and transition metal coordination chemistry of a novel hexadentate bispidine ligand
Reported is the new bispidine-derived hexadentate ligand L (L = 3-(2-methylpyridyl)-7-(bis-2-methylpyridyl)-3,7-diazabicyclo[3.3.1]nonane) with two tertiary amine and four pyridine donor groups. This ligand can form heterodinuclear and mononuclear complexes and, in the mononuclear compounds discusse...
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| Main Authors: | , , |
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| Format: | Article (Journal) |
| Language: | English |
| Published: |
2015
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| In: |
Dalton transactions
Year: 2014, Volume: 44, Issue: 6, Pages: 2724-2736 |
| ISSN: | 1477-9234 |
| DOI: | 10.1039/C4DT03262D |
| Online Access: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C4DT03262D Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2015/dt/c4dt03262d 
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| Author Notes: | Peter Comba, Henning Rudolf and Hubert Wadepohl |
MARC
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| 520 | |a Reported is the new bispidine-derived hexadentate ligand L (L = 3-(2-methylpyridyl)-7-(bis-2-methylpyridyl)-3,7-diazabicyclo[3.3.1]nonane) with two tertiary amine and four pyridine donor groups. This ligand can form heterodinuclear and mononuclear complexes and, in the mononuclear compounds discussed here, the ligand may coordinate as a pentadentate ligand, with one of the bispyridinemethane-based pyridine groups un- or semi-coordinated, or as a hexadentate ligand, leading to a pentagonal pyramidal coordination geometry or, with an additional monodentate ligand, to a heptacoordinate pentagonal bipyramidal structure. The solution and solid state data presented here indicate that, with the relatively small CuII and high-spin FeII ions the fourth pyridine group is only semi-coordinated for steric reasons and, with the larger high-spin MnII ion genuine heptacoordination is observed but with a relatively large distortion in the pentagonal equatorial plane. | ||
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