A short and modular synthesis of bulky and electron-rich N-phosphinomethyl-functionalised N-heterocyclic carbene complexes

Bulky and electron-rich N-phosphinomethyl-substituted N-heterocyclic carbene transition metal complexes have been prepared in a short and efficient protocol. The modular synthesis allows one to convert borane-protected phosphino-functionalized imidazolium salts into their corresponding metal chelate...

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Bibliographic Details
Main Authors: Brill, Marcel (Author) , Kühnel, Erik (Author) , Scriban, Corina (Author) , Rominger, Frank (Author) , Hofmann, Peter (Author)
Format: Article (Journal)
Language:English
Published: 19 July 2013
In: Dalton transactions
Year: 2013, Volume: 42, Issue: 36, Pages: 12861-12864
ISSN:1477-9234
DOI:10.1039/C3DT51777B
Online Access:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C3DT51777B
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2013/dt/c3dt51777b
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Author Notes:Marcel Brill, Erik Kühnel, Corina Scriban, Frank Rominger and Peter Hofmann
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Summary:Bulky and electron-rich N-phosphinomethyl-substituted N-heterocyclic carbene transition metal complexes have been prepared in a short and efficient protocol. The modular synthesis allows one to convert borane-protected phosphino-functionalized imidazolium salts into their corresponding metal chelate complexes in a one-pot procedure.
Item Description:Gesehen am 04.12.2020
Physical Description:Online Resource
ISSN:1477-9234
DOI:10.1039/C3DT51777B