Observation of filamentous nanostructures in organic-inorganic composite thin films deposited by co-evaporation
Nanostructures are important for a wide area of applications, but are very often difficult to fabricate. A novel and basic approach for controlled nanofilament growth in an organic/inorganic composite material is demonstrated. Thin films of MoO3-doped 4′-bis(N-carbazolyl)-1,1′-biphenyl are grown via...
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| Hauptverfasser: | , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
November 21, 2013
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| In: |
Advanced functional materials
Year: 2013, Jahrgang: 23, Heft: 17, Pages: 2130-2136 |
| ISSN: | 1616-3028 |
| DOI: | https://doi.org/10.1002/adfm.201202089 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/adfm.201202089 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/adfm.201202089 
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| Verfasserangaben: | Daniela Donhauser, Martin Pfannmöller, Levin Dieterle, Katrin Schultheiß, Rasmus R. Schröder, Wolfgang Kowalsky, and Michael Kröger |
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| 520 | |a Nanostructures are important for a wide area of applications, but are very often difficult to fabricate. A novel and basic approach for controlled nanofilament growth in an organic/inorganic composite material is demonstrated. Thin films of MoO3-doped 4′-bis(N-carbazolyl)-1,1′-biphenyl are grown via vacuum sublimation and analyzed using advanced electron microscopy and spectroscopy techniques. Using electron spectroscopic imaging in the core-loss and low-loss regime, MoO3 agglomerations are identified for different doping concentrations. A 3D reconstruction of the thin film yielded by electron tomography reveals a filamentous structure of MoO3 within the organic matrix. These filaments are preferentially oriented along the growth direction and are only a few nanometers in diameter. Furthermore, control of the filament growth is possible by changing the substrate temperature because for composites grown on substrates cooled to 120 K MoO3 agglomeration cannot be detected. | ||
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