Single or paired?: Structure and reactivity of PNP-chromium(II) hydrides
The preparation and reactivity of a range of novel paramagnetic chromium(II) complexes supported by a carbazole-based PNP pincer ligand is reported. Deprotonation of the ligand precursors R(PNP)H (1R) and subsequent reaction with chromium(II) chloride led to the formation of square-planar chlorido c...
Gespeichert in:
| Hauptverfasser: | , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
September 15, 2020
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| In: |
Inorganic chemistry
Year: 2020, Jahrgang: 59, Heft: 19, Pages: 14526-14535 |
| ISSN: | 1520-510X |
| DOI: | 10.1021/acs.inorgchem.0c02315 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1021/acs.inorgchem.0c02315
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| Verfasserangaben: | Jonas C. Ott, Daniel Isak, Julian J. Melder, Hubert Wadepohl, Lutz H. Gade |
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| 520 | |a The preparation and reactivity of a range of novel paramagnetic chromium(II) complexes supported by a carbazole-based PNP pincer ligand is reported. Deprotonation of the ligand precursors R(PNP)H (1R) and subsequent reaction with chromium(II) chloride led to the formation of square-planar chlorido complexes R(PNP)CrCl (2R). Further reaction with various alkylating agents resulted in the isolation of chromium alkyl complexes R(PNP)CrR′ (3R-R′) which were then hydrogenated to yield two rare examples of paramagnetic chromium(II) hydrides 4iPr and 4tBu. Both compounds were characterized by X-ray diffraction and paramagnetic NMR spectroscopy supported by a comprehensive DFT-supported assignment of the resonances. While the di(tert-butyl)phosphino PNP substituted complex 4tBu was found to exhibit a monomeric square-planar molecular structure, its isopropyl-substituted analog 4iPr forms a dimer, also indicated by a strong antiferromagnetic coupling of the chromium centers. The pronounced reactivity of these compounds toward C═X double bonds was demonstrated by reaction with benzophenone, N,N′-dicyclohexylcarbodiimide, and carbon dioxide, which gave the corresponding insertion products. The alkoxido complex 5iPr, the amidinato complex 6iPr, and the formato compound 7tBu were also characterized by X-ray diffraction. | ||
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