Polydimethylsiloxane-based wide-range mass calibration for direct analysis in real-time mass spectrometry
Direct analysis in real-time mass spectrometry (DART-MS) is normally applied for small-molecule analysis up to about m/z 1,000. Here, for the analysis of polydimethylsiloxanes, high-mass capabilities expanding beyond m/z 3,000 are demonstrated. In addition, polydimethylsiloxanes provide an ideal mas...
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
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14 August 2013
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| In: |
Analytical and bioanalytical chemistry
Year: 2013, Jahrgang: 405, Heft: 26, Pages: 8663-8668 |
| ISSN: | 1618-2650 |
| DOI: | 10.1007/s00216-013-7287-1 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1007/s00216-013-7287-1
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| Verfasserangaben: | Jürgen H. Gross |
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| 520 | |a Direct analysis in real-time mass spectrometry (DART-MS) is normally applied for small-molecule analysis up to about m/z 1,000. Here, for the analysis of polydimethylsiloxanes, high-mass capabilities expanding beyond m/z 3,000 are demonstrated. In addition, polydimethylsiloxanes provide an ideal mass calibration standard for positive-ion DART-MS. A mass reference list has been compiled to cover ions from m/z 200 up to m/z 2,600. Species with more than 20 silicon atoms exhibit increasingly broader isotopic patterns with decreasing abundances of the monoisotopic ions. The use of the first isotopic peaks for analyte ions above m/z 2,000 serves as a work-around and ensures easy and reproducible recognition of the reference peaks by the instrument data system. Here, the positive-ion DART mass spectra of polydimethylsiloxanes and the corresponding experimental procedures are described, and the mass reference list is provided. | ||
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