Nucleoside-based diarylethene photoswitches and their facile incorporation into photoswitchable DNA
Come into the light: Pyrimidine nucleosides were found to undergo fast and reversible ring closure upon irradiation with light when covalently attached to 2-[2-methyl-5-phenylthien-3-yl]cyclopent-1-ene (see scheme). Synthesis using an aqueous-phase Suzuki-Miyaura cross-coupling allows for one-step c...
Gespeichert in:
| Hauptverfasser: | , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
2013 Feb 12
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| In: |
Angewandte Chemie. International edition
Year: 2013, Jahrgang: 52, Heft: 11, Pages: 3186-3190 |
| ISSN: | 1521-3773 |
| DOI: | https://doi.org/10.1002/anie.201209943 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/anie.201209943 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201209943 
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| Verfasserangaben: | Hana Cahová and Andres Jäschke |
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| 520 | |a Come into the light: Pyrimidine nucleosides were found to undergo fast and reversible ring closure upon irradiation with light when covalently attached to 2-[2-methyl-5-phenylthien-3-yl]cyclopent-1-ene (see scheme). Synthesis using an aqueous-phase Suzuki-Miyaura cross-coupling allows for one-step conversion of iodo-modified oligonucleotides into fully reversible DNA photoswitches. | ||
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