A theoretical DFT-based and experimental study of the transmetalation step in Au/Pd-mediated cross-coupling reactions

In this work a combined theoretical and experimental investigation of the cross-coupling reaction involving two metallic reaction centers, namely gold and palladium, is described. One metal center (Au) hereby is rather inert towards change in its oxidation state, whereas Pd undergoes oxidative inser...

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Bibliographic Details

Main Authors:	Hansmann, Max M. (Author) , Pernpointner, Markus (Author) , Döpp, René (Author) , Hashmi, A. Stephen K. (Author)
Format:	Article (Journal)
Language:	English
Published:	September 25, 2013
In:	Chemistry - a European journal Year: 2013, Volume: 19, Issue: 45, Pages: 15290-15303
ISSN:	1521-3765
DOI:	https://doi.org/10.1002/chem.201301840
Online Access:	Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/chem.201301840 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201301840
Author Notes:	Max M. Hansmann, Markus Pernpointner, René Döpp, and A. Stephen K. Hashmi