Gold(I)-catalyzed domino reaction of allyl 2-en-4-ynyl ethers to 1,3,6-trien-4-yl ketones

The gold(I)-catalyzed reaction of allyl 2-en-4-ynyl ethers provides stereoselectively (Z)-1,3,6-trienes with an acyl substitutent in the 4-position. The reaction proceeds through an oxygen transfer along the chain and a clean allylic inversion. This complements the preceding work by Gagosz, who obta...

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Bibliographic Details

Main Authors:	Hashmi, A. Stephen K. (Author) , Graf, Katharina (Author) , Ackermann, Martin (Author) , Rominger, Frank (Author)
Format:	Article (Journal)
Language:	English
Published:	March 7, 2013
In:	ChemCatChem Year: 2013, Volume: 5, Issue: 5, Pages: 1200-1204
ISSN:	1867-3899
DOI:	https://doi.org/10.1002/cctc.201200787
Online Access:	Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/cctc.201200787 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.201200787
Author Notes:	A. Stephen K. Hashmi, Katharina Graf, Martin Ackermann, and Frank Rominger