Anthracene- pentacene dyads: synthesis and OFET characterization
The synthesis of a series of unsymmetrical derivatives of pentacene appended with functionalized anthracene moieties is reported. These anthracene−pentacene dyads have been characterized by UV-vis spectroscopy and cyclic voltammetry to examine their electronic properties. X-ray crystallographic anal...
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| Hauptverfasser: | , , , , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
04 May 2020
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| In: |
ChemPlusChem
Year: 2020, Jahrgang: 85, Heft: 5, Pages: 921-926 |
| ISSN: | 2192-6506 |
| DOI: | https://doi.org/10.1002/cplu.202000233 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/cplu.202000233 Verlag, lizenzpflichtig, Volltext: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cplu.202000233 
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| Verfasserangaben: | Miriam Hauschild, Lan Chen, Sebastian H. Etschel, Michael J. Ferguson, Frank Hampel, Marcus Halik, and Rik R. Tykwinski |
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| 520 | |a The synthesis of a series of unsymmetrical derivatives of pentacene appended with functionalized anthracene moieties is reported. These anthracene−pentacene dyads have been characterized by UV-vis spectroscopy and cyclic voltammetry to examine their electronic properties. X-ray crystallographic analysis was used to examine the solid-state features of anthracene−pentacene dyads 1 a-d with H−, F−, Cl−, and Br− substituents on the 9-position of anthracene, and shows that the packing arrangement of anthracene−pentacene derivatives 1 b,d,e are remarkably similar irrespective of the presence of fluoride, bromide or methyl substituents. The pentacene−anthracene dyads have been incorporated into OTFTs to evaluate their semiconducting properties. The pentacene derivative 1 b shows ambipolar behavior using AlOx C14PA as the gate dielectric (electron and hole mobilities of 7.6 ⋅ 10−3 and 1.6 ⋅ 10−1 cm2 V−1 s−1), while performance of all derivatives was poor using p-doped Silicon as the substrate. These studies highlight the importance of thin-film formation over molecular structure. | ||
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| 700 | 1 | |a Halik, Marcus |e VerfasserIn |4 aut | |
| 700 | 1 | |a Tykwinski, Rik R. |e VerfasserIn |4 aut | |
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