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A new LiCoPO4 polymorph via low temperature synthesis

Non-olivine LiCoPO4 microcrystals have been synthesized at low temperatures by microwave-assisted hydrothermal synthesis. The resulting octahedra-like micrometer-sized crystals exhibit a Pn21a symmetry and are isostructural to LiZnPO4. The orthorhombic lattice constants are a = 10.023(8) Å, b = 6.7...

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Hauptverfasser: Jähne, Carsten (VerfasserIn) , Neef, Christoph (VerfasserIn) , Koo, Changhyun (VerfasserIn) , Meyer, Hans-Peter (VerfasserIn) , Klingeler, Rüdiger (VerfasserIn)
Dokumenttyp: Article (Journal)
Sprache:Englisch
Veröffentlicht: 04 Jan 2013
In: Journal of materials chemistry. A, Materials for energy and sustainability
Year: 2013, Jahrgang: 1, Heft: 8, Pages: 2856-2862
ISSN:2050-7496
DOI:10.1039/C2TA00118G
Online-Zugang:Verlag, lizenzpflichtig, Volltext: https://doi.org/10.1039/C2TA00118G
Verlag, lizenzpflichtig, Volltext: https://pubs.rsc.org/en/content/articlelanding/2013/ta/c2ta00118g
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Verfasserangaben:Carsten Jähne, Christoph Neef, Changhyun Koo, Hans-Peter Meyer and Rüdiger Klingeler

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520 |a Non-olivine LiCoPO4 microcrystals have been synthesized at low temperatures by microwave-assisted hydrothermal synthesis. The resulting octahedra-like micrometer-sized crystals exhibit a Pn21a symmetry and are isostructural to LiZnPO4. The orthorhombic lattice constants are a = 10.023(8) Å, b = 6.724(7) Å, and c = 4.963(4) Å. The microcrystals are metastable and transform to olivine LiCoPO4 upon heating above T ≈ 220 °C under an argon atmosphere. The magnetic properties confirm a phase pure material with a Co-valence of 2+, and imply long-range antiferromagnetic ordering below TN = 11 K. Electrochemical analysis by means of cyclic voltammetry displays a reversible redox couple at around 5.1 V/4.8 V vs. Li/Li+. 
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