Highly active mononuclear NAC-gold(I) catalysts
One gold is enough: Mononuclear, homogeneous gold catalysts displayed excellent catalytic activity on the order of that previously reported for gold nanoparticle catalysts and surface-bound gold complexes. In the model synthesis of spiro compounds (see picture) extremely high turnover numbers were a...
Gespeichert in:
| Hauptverfasser: | , , , |
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| Dokumenttyp: | Article (Journal) |
| Sprache: | Englisch |
| Veröffentlicht: |
20 June 2013
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| In: |
Angewandte Chemie. International edition
Year: 2013, Jahrgang: 52, Heft: 31, Pages: 7963-7966 |
| ISSN: | 1521-3773 |
| DOI: | https://doi.org/10.1002/anie.201210351 |
| Online-Zugang: | Verlag, lizenzpflichtig, Volltext: https://doi.org/https://doi.org/10.1002/anie.201210351 Verlag, lizenzpflichtig, Volltext: https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201210351 |
| Verfasserangaben: | Maria Camila Blanco Jaimes, Constantin R.N. Böhling, Juan Manuel Serrano‐Becerra, and A. Stephen K. Hashmi |
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| 520 | |a One gold is enough: Mononuclear, homogeneous gold catalysts displayed excellent catalytic activity on the order of that previously reported for gold nanoparticle catalysts and surface-bound gold complexes. In the model synthesis of spiro compounds (see picture) extremely high turnover numbers were achieved with only 0.000001 mol % of a silsesquioxane-substituted catalyst. | ||
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